Citation: Zhai Xiao-Yong, Wang Xiao-Qing, Ding Yi-Xuan, Zhou Yong-Gui. Partially biobased polymers: The synthesis of polysilylethers via dehydrocoupling catalyzed by an anionic iridium complex[J]. Chinese Chemical Letters, ;2020, 31(5): 1197-1200. doi: 10.1016/j.cclet.2019.07.017 shu

Partially biobased polymers: The synthesis of polysilylethers via dehydrocoupling catalyzed by an anionic iridium complex

a.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

ygzhou@dicp.ac.cn

Received Date: 18 May 2019
Revised Date: 1 July 2019
Accepted Date: 5 July 2019
Available Online: 5 July 2019

Figures(1)

Partially biobased polysilylethers (PSEs) are synthesized via dehydrocoupling polymerization catalyzed by an anionic iridium complex. Different types (AB type or AA and BB type) of monomers are suitable. Levulinic acid (LA) and succinic acid (SA) have been ranked within the top 10 chemicals derived from biomass. BB type monomers (diols) derived from LA and SA have been applied to the synthesis of PSEs. The polymerization reactions employ an air-stable anionic iridium complex bearing a functional bipyridonate ligand as catalyst. Moderate to high yields of polymers with number-average molecular weights (M_n) up to 4.38× 10⁴ were obtained. A possible catalytic cycle via an Ir-H species is presented. Based on the results of kinetic experiments, apparent activation energy of polymerization in the temperature range of 0-10 ℃ is about 38.6 kJ/mol. The PSEs synthesized from AA and BB type monomers possess good thermal stability (T₅=418 ℃ to 437 ℃) and low glass-transition temperature (T_g=-49.6 ℃).
- Biodegradable polymers,
- Polysilylethers,
- Iridium catalysis,
- Dehydrocoupling polymerization,
- Levulinic acid
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沈阳化工大学材料科学与工程学院沈阳 110142