Citation: Shen Yanbin, Yahao Li Li, Deng Shengjue, Pan Guoxiang, Xiong Qinqin, Ding Xiaokun, Lu Yangfan, Liu Qi, Xia Xinhui, Wang Xiuli, Tu Jiangping. TiC/C core/shell nanowires arrays as advanced anode of sodium ion batteries[J]. Chinese Chemical Letters, ;2020, 31(3): 846-850. doi: 10.1016/j.cclet.2019.06.044 shu

TiC/C core/shell nanowires arrays as advanced anode of sodium ion batteries

Shen Yanbin ^a ,
Yahao Li Li ^a ,
Deng Shengjue ^a ,
Pan Guoxiang ^b ,
Xiong Qinqin ^c ,
Ding Xiaokun ^d ,
Lu Yangfan ^a ,
Liu Qi ^e ,
Xia Xinhui ^a,f,*, ,
Wang Xiuli ^a ,
Tu Jiangping ^a,*,

a.
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
b.
Department of Materials Chemistry, Huzhou University, Huzhou 313000, China
c.
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
d.
Department of Chemistry, Zhejiang University, Hangzhou 310027, China
e.
Department of Physics, City University of Hong Kong, Hong Kong 999077, China
f.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

helloxxh@zju.edu.cn

tujp@zju.edu.cn

Received Date: 23 May 2019
Revised Date: 19 June 2019
Accepted Date: 20 June 2019
Available Online: 24 June 2019

Figures(4)

High-performance anodes of sodium ion batteries (SIBs) largely depends on rational architecture design and binder-free smart hybridization. Herein, we report TiC/C core/shell nanowires arrays prepared by a one-step chemical vapor deposition (CVD) method and apply it as the anode of SIBs for the first time. The conductive TiC core is intimately decorated with carbon shell. The as-obtained TiC/C nanowires are homogeneously grown on the substrate and show core/shell heterostructure and porous architecture with high electronic conductivity and reinforced stability. Owing to these merits, the TiC/C electrode displays good rate performance and outstanding cycling performance with a capacity of 135.3 mAh/g at 0.1 A/g and superior capacity retention of 90.14% after 1000 cycles at 2 A/g. The reported strategy would provide a promising way to construct binder-free arrays electrodes for sodium ion storage.
- Sodium ion batteries,
- Nanowires,
- Core/shell structure,
- Carbon,
- Titanium carbide
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