Citation: Sheng Kai, Tian Xuefei, Jagodič Marko, Jagličić Zvonko, Zhang Na, Liu Qing-Yun, Tung Chen-Ho, Sun Di. Synthesis, structure and magnetism of a novel Cu₄^ⅡTi₅^Ⅳ heterometallic cluster[J]. Chinese Chemical Letters, ;2020, 31(3): 809-812. doi: 10.1016/j.cclet.2019.05.050 shu

Synthesis, structure and magnetism of a novel Cu₄^ⅡTi₅^Ⅳ heterometallic cluster

Sheng Kai ^a,b ,
Tian Xuefei ^a ,
Jagodič Marko ^c,*, ,
Jagličić Zvonko ^c ,
Zhang Na ^a,*, ,
Liu Qing-Yun ^d ,
Tung Chen-Ho ^a ,
Sun Di ^a,e,*,

a.
Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China
b.
School of Aeronautics, Shandong Jiaotong University, Ji'nan 250037, China
c.
Faculty of Civil and Geodetic Engineering & Institute of Mathematics, Physics and Mechanics, University of Ljubljana, Ljubljana 1000, Slovenia
d.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
e.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China

^**

marko.jagodic@imfm.si

nzhang@email.sdu.edu.cn

dsun@sdu.edu.cn

Received Date: 26 April 2019
Revised Date: 23 May 2019
Accepted Date: 24 May 2019
Available Online: 25 May 2019

Figures(5)

A nonanuclear Cu₄^ⅡTi₅^Ⅳ heterometallic cluster, [Ti₅Cu₄O₆(ba)₁₆] (1, Hba=benzoic acid) was synthesized in one-pot reaction under the solvothermal condition. The metallic skeleton 1 contains a Ti₅ core constructed from two vertex-shared Ti3 triangles and four separated Cu atoms outside which are connected together by μ₃-O^2- ions. Total 16 ba^- ligands adopt μ₂-η¹:η¹ coordination mode to protect the overall heterometallic core. Due to the unique d-d transitions of Cu^Ⅱ ion, the reflectance spectrum of 1 displays broad and strong absorption towards visible light extending to the near-infrared region. Moreover, 1 shows almost purely paramagnetic behavior with the presence of weak antiferromagnetic interactions at low temperatures.
- Heterometallic cluster,
- Titanium,
- Copper,
- Magnetic property,
- Narrow bandgap
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Synthesis, structure and magnetism of a novel Cu₄^ⅡTi₅^Ⅳ heterometallic cluster