Citation: Xu Dingdian, Zhou Wei, Li Shujing, Bai Dongsheng. Ba₃LaNa(PO₄)₃F:Tm³⁺, Dy³⁺: A tunable blue-white color emitting phosphor via energy transfer for UV white LEDs[J]. Chinese Chemical Letters, ;2020, 31(2): 575-578. doi: 10.1016/j.cclet.2019.04.046 shu

Ba₃LaNa(PO₄)₃F:Tm³⁺, Dy³⁺: A tunable blue-white color emitting phosphor via energy transfer for UV white LEDs

Xu Dingdian ^a,b ,
Zhou Wei ^a,b,*, ,
Li Shujing ^b,*, ,
Bai Dongsheng ^b

a.
Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China
b.
Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China

zhouw@th.btbu.edu.cn

lishujing@th.btbu.edu.cn

Received Date: 19 March 2019
Revised Date: 1 April 2019
Accepted Date: 17 April 2019
Available Online: 18 April 2019

Figures(4)

A series of Tm³⁺/Dy³⁺ co-doped Ba₃LaNa(PO₄)₃F (BLNPF) phosphors were synthesized successfully via a high-temperature solid-reaction, and luminescence properties were investigated. Upon near violet excitation, BLNPF:Tm³⁺, Dy³⁺ phosphors exhibit Tm³⁺:¹D₂-³F₄ and Dy³⁺:⁴F_9/2-⁶H_J (J = 15/2, 13/2, 11/2) transitions with different luminescence intensity. The emitting color of the obtained products was found to shift from blue to white as a result of efficient energy transfer (ET) from Tm³⁺ to Dy³⁺ ions. According to photoluminescence emission intensity, the positive effect of activator on ETefficiency was calculated and the maximum ET efficiency was found around 72.6% with Dy³⁺ concentration was 0.04. By means of Dexter's theoretical model, furthermore, dipole-dipole interaction was confirmed as the mechanism of energy transfer from Tm³⁺ to Dy³⁺ ions. The results suggested that BLNPF:Tm³⁺, Dy³⁺ phosphor might be a promising single-phased white-light-emitting phosphor for UV white-light LED.
- Phosphors,
- Ba₃LaNa(PO₄)₃F,
- Luminescence,
- Energy transfer,
- White light
1. [1]
  N. Guo, Y.J. Huang, Y.C. Jia, et al., Dalton Trans. 42 (2013) 941-947. doi: 10.1039/C2DT31657A
2. [2]
  C. Feldmann, T. Jüstel, C.R. Ronda, P. Schmidt, Adv. Funct. Mater. 13 (2010) 511-516.
3. [3]
  C.C. Lin, R.S. Liu, J. Phys. Chem. Lett. 2 (2011) 1268. doi: 10.1021/jz2002452
4. [4]
  M.L. Zhang, Z.G. Xia, M.S. Molokeev, L. Shi, Q.L. Liu, J. Mater. Chem. C 4 (2016) 9078-9084. doi: 10.1039/C6TC03373C
5. [5]
  H. Okamoto, K. Kasuga, I. Hara, Y. Kubota, Opt. Express 17 (2009) 20227-20232. doi: 10.1364/OE.17.020227
6. [6]
  S.F. Gao, C.L. Sun, Y.X. Ji, et al., Mater. Express 3 (2013) 127-134. doi: 10.1166/mex.2013.1107
7. [7]
  X.F. Wang, Q. Liu, Y.Y. Bu, et al., RSC Adv. 5 (2015) 86219-86236. doi: 10.1039/C5RA16986K
8. [8]
  Y.H. Zheng, X. Sun, H.J. Su, L.B. Sun, C.X. Qi, Mater. Res. Bull.105 (2018) 149-153. doi: 10.1016/j.materresbull.2018.04.031
9. [9]
  L. Guerbous, M. Derbal, J.P. Chaminade, J. Lumin. 130 (2010) 2469-2475. doi: 10.1016/j.jlumin.2010.08.014
10. [10]
  K. Li, Y. Zhang, X.J. Li, et al., Phys. Chem. Chem. Phys. 17 (2015) 4283-4292. doi: 10.1039/C4CP03894K
11. [11]
  Z.L. Fu, X.J. Wang, Y.M. Yang, et al., Dalton Trans. 43 (2014) 2819-2827. doi: 10.1039/C3DT52231H
12. [12]
  Z.G. Xia, R.S. Liu, K.W. Huang, et al., J. Mater. Chem. 22 (2012) 15183-15189. doi: 10.1039/c2jm32733c
13. [13]
  S.S. Hu, W.J. Tang, J. Lumin. 145 (2014) 100-104. doi: 10.1016/j.jlumin.2013.07.044
14. [14]
  Z.Q. Hu, Y. Guo, J.H. Zhang, Y.J. Zhang, J. Mater. Sci. 53 (2018) 6414-6423. doi: 10.1007/s10853-017-1947-z
15. [15]
  A.X. Guan, C.Y. Yao, G.F. Wang, et al., Luminescence 32 (2017) 529-534. doi: 10.1002/bio.3208
16. [16]
  D.L. Monika, H. Nagabhushana, R.H. Krishna, et al., RSC Adv. 4 (2014) 38655-38662. doi: 10.1039/C4RA04655B
17. [17]
  F. Zhang, T. Zhang, G.Q. Li, W.F. Zhang, J. Alloys Compd. 618 (2015) 484-487. doi: 10.1016/j.jallcom.2014.08.178
18. [18]
  G.M. Cai, N. Yang, H.X. Liu, J.Y. Si, Y.Q. Zhang, J. Lumin. 187 (2017) 211-220. doi: 10.1016/j.jlumin.2017.03.017
19. [19]
  J. Wang, Y.H. Xu, M. Hojamberdiev, et al., J. Alloys. Compd. 479 (2009) 772-776. doi: 10.1016/j.jallcom.2009.01.076
20. [20]
  S.F. Gao, S. Xu, Y.Q. Wang, C.Y. Tu, J. Lumin. 178 (2016) 282-287. doi: 10.1016/j.jlumin.2016.05.040
21. [21]
  G.V. Lokeswara, L.R. Moorthy, P. Packiyaraj, B.C. Jamalaiah, Opt. Mater. 35 (2013) 2138-2145. doi: 10.1016/j.optmat.2013.05.038
22. [22]
  H.Y. Wu, J.F. Yang, X.X. Wang, Solid. State. Sci. 79 (2018) 85-92. doi: 10.1016/j.solidstatesciences.2018.02.009
23. [23]
  J. Zhou, Q.L. Liu, Z.G. Xia, J. Mater. Chem. C 6 (2018) 4371-4383. doi: 10.1039/C8TC01043A
24. [24]
  A.M. Latshaw, K.D. Hughey, M.D. Smith, et al., Inorg. Chem. 54 (2014) 876-884.
25. [25]
  Q.F. Guo, B. Ma, L.B. Liao, et al., Cream. Int. 42 (2016) 11687-11691. doi: 10.1016/j.ceramint.2016.04.086
26. [26]
  Y.X. Cao, X. Ding, Y.H. Wang, J. Am. Cream. Soc. 99 (2016) 3696-3704. doi: 10.1111/jace.14394
27. [27]
  W.T. Zhang, M. Yu, Z.Q. Wu, Y.Q. Wang, P.C. Zhang, J. Mater. Sci. 29 (2018) 8224-8233.
28. [28]
  M.H. Tong, Y.J. Liang, G.G. Li, Z.G. Xia, F. Yang, Opt. Mater. 36 (2014) 1566-1570. doi: 10.1016/j.optmat.2014.04.026
29. [29]
  J.C. Joshi, B.C. Joshi, N.C. Pandey, R. Belwal, J. Joshi, J. Solid State Chem. 22 (1977) 439-443. doi: 10.1016/0022-4596(77)90021-4
30. [30]
  G. Blasse, J. Solid State Chem. 62 (1986) 207-211. doi: 10.1016/0022-4596(86)90233-1
31. [31]
  Y. Tian, N.N. Feng, M.W. Wieczorek, et al., Dyes Pigm. 131 (2016) 91-99. doi: 10.1016/j.dyepig.2016.04.010
32. [32]
  D.L. Dexter, J.H. Schulman, J. Chem. Phys. 22 (1954) 1063-1066. doi: 10.1063/1.1740265
33. [33]
  Q. Zhang, X.C. Wang, X. Ding, Y.T. Wang, Dyes Pigm. 149 (2018) 268-275. doi: 10.1016/j.dyepig.2017.10.004
34. [34]
  D. Qin, W.J. Tang, RSC Adv. 6 (2016) 45376-45385. doi: 10.1039/C6RA10763J
1. [1]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
2. [2]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
3. [3]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
4. [4]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
5. [5]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
6. [6]
  Chun-Yun Ding , Ru-Yuan Zhang , Yu-Wu Zhong , Jiannian Yao . Binary and heterostructured microplates of iridium and ruthenium complexes: Preparation, characterization, and thermo-responsive emission. Chinese Journal of Structural Chemistry, 2024, 43(10): 100393-100393. doi: 10.1016/j.cjsc.2024.100393
7. [7]
  Er-Meng Wang , Ziyi Wang , Xu Ban , Xiaowei Zhao , Yanli Yin , Zhiyong Jiang . Chemoselective photocatalytic sulfenylamination of alkenes with sulfenamides via energy transfer. Chinese Chemical Letters, 2024, 35(12): 109843-. doi: 10.1016/j.cclet.2024.109843
8. [8]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
9. [9]
  Yi Zhu , Jingyan Zhang , Yuchao Zhang , Ying Chen , Guanghui An , Ren Liu . Designing unimolecular photoinitiator by installing NHPI esters along the TX backbone for acrylate photopolymerization and their applications in coatings and 3D printing. Chinese Chemical Letters, 2024, 35(7): 109573-. doi: 10.1016/j.cclet.2024.109573
10. [10]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
11. [11]
  Supphachok Chanmungkalakul , Syed Ali Abbas Abedi , Federico J. Hernández , Jianwei Xu , Xiaogang Liu . The dark side of cyclooctatetraene (COT): Photophysics in the singlet states of “self-healing” dyes. Chinese Chemical Letters, 2024, 35(8): 109227-. doi: 10.1016/j.cclet.2023.109227
12. [12]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
13. [13]
  Zhu Shu , Xin Lei , Yeye Ai , Ke Shao , Jianliang Shen , Zhegang Huang , Yongguang Li . ATP-induced supramolecular assembly based on chromophoric organic molecules and metal complexes. Chinese Chemical Letters, 2024, 35(11): 109585-. doi: 10.1016/j.cclet.2024.109585
14. [14]
  Pengfei Li , Chulin Qu , Fan Wu , Hu Gao , Chengyan Zhao , Yue Zhao , Zhen Shen . Robust free-base and metalated corrole radicals with reduction-induced emission. Chinese Chemical Letters, 2025, 36(2): 110292-. doi: 10.1016/j.cclet.2024.110292
15. [15]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
16. [16]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
17. [17]
  Zhao-Xia Lian , Xue-Zhi Wang , Chuang-Wei Zhou , Jiayu Li , Ming-De Li , Xiao-Ping Zhou , Dan Li . Producing circularly polarized luminescence by radiative energy transfer from achiral metal-organic cage to chiral organic molecules. Chinese Chemical Letters, 2024, 35(8): 109063-. doi: 10.1016/j.cclet.2023.109063
18. [18]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
19. [19]
  Xiaoyao Ma , Jinling Zhang , Ge Fang , He Gao , Jie Gao , Li Fu , Yuanyuan Hou , Gang Bai . Förster resonance energy transfer reveals phillygenin and swertiamarin concurrently target AKT on different binding domains to increase the anti-inflammatory effect. Chinese Chemical Letters, 2024, 35(5): 108823-. doi: 10.1016/j.cclet.2023.108823
20. [20]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1167)
HTML views(98)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ba3LaNa(PO4)3F:Tm3+, Dy3+: A tunable blue-white color emitting phosphor via energy transfer for UV white LEDs

Metrics

通讯作者: 陈斌, bchen63@163.com

Ba₃LaNa(PO₄)₃F:Tm³⁺, Dy³⁺: A tunable blue-white color emitting phosphor via energy transfer for UV white LEDs