Citation: Huang Ge, Wang Yue, Liu Tianfu. A low-temperature synthesis-induced defect formation strategy for stable hierarchical porous metal-organic frameworks[J]. Chinese Chemical Letters, ;2019, 30(12): 2309-2312. doi: 10.1016/j.cclet.2019.04.030 shu

A low-temperature synthesis-induced defect formation strategy for stable hierarchical porous metal-organic frameworks

Huang Ge ^a,1 ,
Wang Yue ^b,1, ,
Liu Tianfu ^a,*,

a.
Fujian Institute of Research on the Structure of Matter, State Key Laboratory of Structural Chemistry, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067, China

wangyue@cque.edu.cn

tfliu@fjirsm.ac.cn

Received Date: 18 March 2019
Revised Date: 8 April 2019
Accepted Date: 12 April 2019
Available Online: 13 December 2019

Figures(3)

A stable hierarchical porous metal-organic framework PCN-56 with abundant Lewis acid sites (denoted as Defective-PCN-56) was synthesized by the low-temperature synthesis-induced defect formation method. The existence of mesopore in structure was confirmed by N₂ sorption isotherm and the successful encapsulation of large dye molecules. The Defective-PCN-56 has higher loading capacity toward anti-cancer drug Doxo compared with that of "nearly ideal-crystal" (denoted as Ideal-PCN-56) synthesized at high temperature, showing potential application as drug carrier. The low-temperature synthesis-induced defect formation strategy presented here provides a new and facile way to synthesize stable MOFs with the combination of intrinsic micropore and additional mesopore as well as abundant Lewis acid sites.
- Low-temperature induced,
- Defect formation strategy,
- Stable MOFs,
- Hierarchical porous MOFs,
- Lewis acid sites
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