Citation: Li Yunong, Wang Lei, Low Jingxiang, Wu Di, Hu Canyu, Jiang Wenbin, Ma Jun, Wang Chengming, Long Ran, Song Li, Xu Hangxun, Xiong Yujie. Integrating bimetallic AuPd nanocatalysts with a 2D aza-fused π-conjugated microporous polymer for light-driven benzyl alcohol oxidation[J]. Chinese Chemical Letters, ;2020, 31(1): 231-234. doi: 10.1016/j.cclet.2019.04.022 shu

Integrating bimetallic AuPd nanocatalysts with a 2D aza-fused π-conjugated microporous polymer for light-driven benzyl alcohol oxidation

Hefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230026, China

Received Date: 20 February 2019
Revised Date: 4 April 2019
Accepted Date: 10 April 2019
Available Online: 13 January 2019

Figures(4)

Efficient catalytic system with low energy consumption exhibits increasing importance due to the upcoming energy crisis. Given this situation, it should be an admirable strategy for reducing energy input by effectively utilizing incident solar energy as a heat source during catalytic reactions. Herein, aza-fused π-conjugated microporous polymer (aza-CMP) with broad light absorption and high photothermal conversion efficiency was synthesized and utilized as a support for bimetallic AuPd nanocatalysts in light-driven benzyl alcohol oxidation. The AuPd nanoparticles anchored on aza-CMP (aza-CMP/Au_xPd_y) exhibited excellent catalytic performance for benzyl alcohol oxidation under 50 mW/cm² light irradiation. The improved catalytic performance by the aza-CMP/Au_xPd_y is attributed to the unique photothermal effect induced by aza-CMP, which can promote the catalytic benzyl alcohol oxidation occurring at AuPd. This work presents a novel approach to effectively utilize solar energy for conventional catalytic reactions through photothermal effect.
- Aza-CMP,
- AuPd,
- Photothermal,
- Benzyl alcohol oxidation,
- Catalysis
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