Citation: Wu Yi-Peng, Yan Meng, Gao Zhong-Zheng, Hou Jun-Li, Wang Hui, Zhang Dan-Wei, Zhang Junliang, Li Zhan-Ting. Ruthenium(Ⅱ)-cored supramolecular organic framework-mediated recyclable visible light photoreduction of azides to amines and cascade formation of lactams[J]. Chinese Chemical Letters, ;2019, 30(7): 1383-1386. doi: 10.1016/j.cclet.2019.03.056 shu

Ruthenium(Ⅱ)-cored supramolecular organic framework-mediated recyclable visible light photoreduction of azides to amines and cascade formation of lactams

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Centre of Chemistry for Energy Materials(iChEM), Fudan University, Shanghai 200433, China

Houjl@fudan.edu.cn

junliangzhang@fudan.edu.cn

ztli@fudan.edu.cn

Received Date: 27 February 2019
Revised Date: 19 March 2019
Accepted Date: 21 March 2019
Available Online: 31 July 2019

Figures(1)

Ru(bpy)₃]²⁺-cored supramolecular organic framework SMOF-1, assembled from a [Ru(bpy)₃]²⁺-derived hexaarmed molecule and cucurbit[8]uril, has been demonstrated to heterogeneously catalyze visible light-induced reduction of phenyl, benzyl, 2-phenylethyl and 3-phenylpropyl azides in acetonitrile to produce the corresponding amines in good to high yields. For the last two kinds of azides that bear a CO₂Me group at the para-position of the benzene ring, cascade reactions take place to generate the corresponding lactams in high yields. Compared with homogeneous control [Ru(bpy)₃]Cl₂, SMOF-1 exhibits remarkably increased photocatalysis activity as a result of synergistic effect of the [Ru(bpy)₃]²⁺ units that form cubic cages to host the azide molecules and related intermediates. Moreover, SMOF-1 displays high recyclability and considerable photocatalysis activity after 3 to 12 runs.
- Supramolecular organic framework,
- Visible light photocatalysis,
- Recyclability,
- Azide reduction,
- Amine,
- Lactam
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