Citation: Li Yue, Wang Xia, Xing Chengyong, Zhang Xiurong, Liang Zelong, Wang Xiaokang, Zhang Kai, Wang Yutong, Liu Di, Fan Weidong, Dai Fangna. Two alkynyl functionalized Co(Ⅱ)-MOFs as fluorescent sensors exhibiting selectivity and sensitivity for Fe³⁺ and nitroaromatic compounds[J]. Chinese Chemical Letters, ;2019, 30(7): 1440-1444. doi: 10.1016/j.cclet.2019.03.014 shu

Two alkynyl functionalized Co(Ⅱ)-MOFs as fluorescent sensors exhibiting selectivity and sensitivity for Fe³⁺ and nitroaromatic compounds

Li Yue ^a,1 ,
Wang Xia ^a,1 ,
Xing Chengyong ^a ,
Zhang Xiurong ^a ,
Liang Zelong ^b ,
Wang Xiaokang ^a ,
Zhang Kai ^a ,
Wang Yutong ^a ,
Liu Di ^c ,
Fan Weidong ^a,*, ,
Dai Fangna ^a,*,

a.
School of Materials Science and Engineering, College of Science, China University of Petroleum(East China), Qingdao 266580, China
b.
College of Chemical Engineering, China University of Petroleum(East China), Qingdao 266580, China
c.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China

weidongfan@163.com

fndai@upc.edu.cn

Received Date: 18 February 2019
Revised Date: 2 March 2019
Accepted Date: 6 March 2019
Available Online: 7 July 2019

Figures(4)

Two Co(Ⅱ)-MOFs with different structures were successfully synthesized under the premise of designing two ligands containing alkynyl functional groups. Complexes 1 ([Co(TEPA)(TPT)_2/3]·2DMF·H₂O) and 2 ([Co(EPA)(TPT)]·1.5DMF·1.5H₂O) show excellent luminescence properties. Meanwhile, as fluorescent sensors, complexes 1 and 2 exhibit selectivity and sensitivity for Fe³⁺ with the K_sv of 1.520 ×10⁴ L/mol and 3.543×10⁴ L/mol, which can rapidly detect nitroaromatic compounds in methanol and ethanol, especially for 2, 4-NPH through fluorescence quenching with high quenching efficiency. In particular, the K_sv value of complexes 1 and 2 towards 2, 4-NPH can reach up to 1.627×10⁵ L/mol and 9.600×10⁴ L/mol, demonstrating that complexes 1 and 2 are good candidates for the identification and detection of Fe³⁺ and nitroaromatic compounds.
- Metal-organic frameworks,
- Alkynyl functionalized,
- Fluorescence sensor,
- Fe³⁺ ion,
- Nitroaromatic compounds
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沈阳化工大学材料科学与工程学院沈阳 110142

Two alkynyl functionalized Co(Ⅱ)-MOFs as fluorescent sensors exhibiting selectivity and sensitivity for Fe3+ and nitroaromatic compounds

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通讯作者: 陈斌, bchen63@163.com

Two alkynyl functionalized Co(Ⅱ)-MOFs as fluorescent sensors exhibiting selectivity and sensitivity for Fe³⁺ and nitroaromatic compounds