Citation: Zhu Na, Lian Zhihua, Zhang Yan, Shan Wenpo, He Hong. Improvement of low-temperature catalytic activity over hierarchical Fe-Beta catalysts for selective catalytic reduction of NO_x with NH₃[J]. Chinese Chemical Letters, ;2019, 30(4): 867-870. doi: 10.1016/j.cclet.2019.03.011 shu

Improvement of low-temperature catalytic activity over hierarchical Fe-Beta catalysts for selective catalytic reduction of NO_x with NH₃

Zhu Na ^a,b,1 ,
Lian Zhihua ^a,1 ,
Zhang Yan ^a,c ,
Shan Wenpo ^a,c,*, ,
He Hong ^a,b,c,d

a.
Center for Excellence in Regional Atmospheric Environment and Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Ningbo Urban Environment Observation and Research Station-NUEORS, Institute of Urban Environment, Chinese Academy of Sciences, Ningbo 315800, China
d.
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China

wpshan@iue.ac.cn

Received Date: 27 January 2019
Revised Date: 1 March 2019
Accepted Date: 5 March 2019
Available Online: 7 April 2019

Figures(4)

Hierarchical Fe-Beta obtained by hydrothermal synthesis exhibited higher low-temperature NH₃-SCR activity than conventional Fe-Beta. In order to identify the main factors leading to the difference in catalytic activity, we investigated the pore structure, acidity and Fe sites of the hierarchical Fe-Beta and conventional Fe-Beta. The enhanced activity of hierarchical Fe-Beta was mainly due to the increase of the quantity of active Fe species. NH₃-TPD and DRIFTS results of NH₃ adsorption clearly verified that hierarchical Fe-Beta had more Lewis acid sites, which is beneficial to the adsorption and activation of NH₃. The H₂-TPR, UV-vis DRS, and EPR results confirmed that the hierarchical Fe-Beta had more isolated active Fe species, which may be associated with that the hierarchical structure introduced more structural defects as ion-exchange sites. Based on the analysis of kinetics experiments and the abovementioned characterizations, it can be concluded that the improvement of NH₃-SCR activity was not due to an intrinsic effect of the specific structural characteristics, but was related to more Fe active sites and better dispersion of Fe species in the hierarchical Fe-Beta.
- Hierarchical structure,
- Fe-Beta,
- NH₃-SCR,
- Low-temperature activity,
- Kinetics
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沈阳化工大学材料科学与工程学院沈阳 110142

Improvement of low-temperature catalytic activity over hierarchical Fe-Beta catalysts for selective catalytic reduction of NOx with NH3

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通讯作者: 陈斌, bchen63@163.com

Improvement of low-temperature catalytic activity over hierarchical Fe-Beta catalysts for selective catalytic reduction of NO_x with NH₃