Citation: Wang Chengfei, Zhang Wei, Li Wenwu, Zhang Yuanyuan, Tang Xiaodong, Hu Ming. Magnetism tuned by intercalation of various metal ions in coordination polymer[J]. Chinese Chemical Letters, ;2019, 30(7): 1390-1392. doi: 10.1016/j.cclet.2019.03.007 shu

Magnetism tuned by intercalation of various metal ions in coordination polymer

State Key Laboratory of Precision Spectroscopy, Key Laboratory of Polar Materials and Devices(MOE), School of Physics and Materials Science, East China Normal University, Shanghai 200241, China

wwli@ee.ecnu.edu.cn

yyzhang@ee.ecnu.edu.cn

mhu@phy.ecnu.edu.cn

Received Date: 30 January 2019
Revised Date: 27 February 2019
Accepted Date: 4 March 2019
Available Online: 5 July 2019

Figures(3)

Incorporation of guest ions into porous frameworks changed magnetism of the host materials significantly. However, in most cases, the guest ions were monovalent due to lack of reliable method to insert divalent and trivalent guest ions. In this work, we demonstrated that divalent and trivalent metal ions could be inserted into frameworks of a coordinate polymer, Cu₃[Fe(CN)₆]₂, through electrochemical intercalation. The magnetism of the host frameworks was changed among paramagnetic, superparamagnetic, and ferromagnetic as demonstrated by physical property measurement system (PPMS). Furthermore, the magnetization of the frameworks under low temperatures correlated to the guest ions significantly. The ionic radius and net charge of the guest ions influenced the intercalation amount of the guest ions, therefore affected the valence change of Fe³⁺ ions in the host frameworks, finally leading to variation of the magnetism of the host materials.
- Electrochemistry,
- Magnetism,
- Guest ions,
- Prussian Blue analogues
1. [1]
  B.V. Harbuzaru, A. Corma, F. Rey, et al., Angew. Chem. Int. Ed. 47 (2008) 1080-1083.
2. [2]
  H.J. Richter, A. Lyberatos, U. Nowak, R.F.L. Evans, R.W. Chantrell, J. Appl. Phys. 111 (2012) 033909. doi: 10.1063/1.3681297
3. [3]
  S. Jadoon, A. Waseem, M. Yaqoob, A. Nabi, Chin. Chem. Lett. 21 (2010) 712-715. doi: 10.1016/j.cclet.2009.11.013
4. [4]
  H. Zhang, F. Huang, D.L. Liu, P. Shi, Chin. Chem. Lett. 26 (2015) 1137-1143. doi: 10.1016/j.cclet.2015.05.026
5. [5]
  P.A. Sundaram, R. Augustine, M. Kannan, Biotechnol. Bioprocess Eng. 17 (2012) 835-840. doi: 10.1007/s12257-011-0582-9
6. [6]
  S. Wu, A.Z. Sun, F. Zhai, A.A. Volinsky, et al., Mater. Lett. 65 (2011) 1882-1884. doi: 10.1016/j.matlet.2011.03.065
7. [7]
  M. Hu, J.S. Jiang, F.X. Bu, et al., RSC Adv. 2 (2012) 4782-4786. doi: 10.1039/c2ra01190e
8. [8]
  M. Darbandi, F. Stromberg, J. Landers, et al., J. Phys. D Appl. Phys. 45 (2012) 195001. doi: 10.1088/0022-3727/45/19/195001
9. [9]
  O.M. Lemine, K. Omri, B. Zhang, et al., Uperlattices Microstruct. 52 (2012) 793-799. doi: 10.1016/j.spmi.2012.07.009
10. [10]
  G.H. Gao, R.R. Shi, W.Q. Qin, et al., J. Mater. Sci. 45 (2010) 3483-3489. doi: 10.1007/s10853-010-4378-7
11. [11]
  H. Xu, B.W. Zeiger, K.S. Suslick, Chem. Soc. Rev. 42 (2013) 2555-2567. doi: 10.1039/C2CS35282F
12. [12]
  L. Wu, H. Yao, B. Hu, S.H. Yu, Chem. Mater. 23 (2011) 3946-3952. doi: 10.1021/cm2013736
13. [13]
  D.P. Dong, J.Q. Xiao, P.F. Zhuang, et al., Inorg. Chem. Commun. 21 (2012) 84-87. doi: 10.1016/j.inoche.2012.04.019
14. [14]
  D.P. Dong, H. Zheng, L. Zhao, et al., Sci. China Chem. 55 (2012) 1018-1021. doi: 10.1007/s11426-012-4597-7
15. [15]
  R.M. Wen, S.D. Han, H. Wang, Y.H. Zhang, Chin. Chem. Lett. 25 (2014) 854-858. doi: 10.1016/j.cclet.2014.05.026
16. [16]
  S. Ohkoshi, T. Matsuda, H. Tokoro, K. Hashimoto, Chem. Mater. 17 (2005) 81-84. doi: 10.1021/cm048461x
17. [17]
  C. Eugenio, G.L.M. Carmen, K. Tomasz, et al., J. Am. Chem. Soc.130 (2008) 15519. doi: 10.1021/ja8047046
18. [18]
  K. Noriyuki, H. Masanori, K. Izuru, et al., J. Am. Chem. Soc. 131 (2009) 212. doi: 10.1021/ja806879a
19. [19]
  M. Nishino, K. Boukheddaden, S. Miyashita, F. Varret, Phys. Rev. B 72 (2005) 73-80.
20. [20]
  T. Liu, H. Zheng, S. Kang, et al., Nat. Commun. 4 (2013) 3826.
21. [21]
  B. Li, R.J. Wei, J. Tao, et al., J. Am. Chem. Soc. 132 (2010) 1558-1566. doi: 10.1021/ja909695f
22. [22]
  Q.Y. Zhang, X. Luo, L.N. Wang, et al., Nano Lett. 16 (2016) 583. doi: 10.1021/acs.nanolett.5b04276
23. [23]
  Y.N. Yan, X.J. Zhou, F. Li, et al., Appl. Phys. Lett. 107 (2015) 122407. doi: 10.1063/1.4931752
24. [24]
  X.J. Zhou, Y.N. Yan, M. Jiang, et al., J. Phys. Chem. C 120 (2016) 1633-1639. doi: 10.1021/acs.jpcc.5b10794
25. [25]
  D.A. Gilbert, J. Olamit, R.K. Dumas, et al., Nat. Commun. 7 (2016) 11050. doi: 10.1038/ncomms11050
26. [26]
  M. Okubo, K. Kagesawa, Y. Mizuno, et al., Inorg. Chem. 52 (2013) 3772-3779. doi: 10.1021/ic302364d
27. [27]
  K. Taniguchi, K. Narushima, J. Mahin, W. Kosaka, H. Miyasaka, Angew. Chem. Int. Ed. 55 (2016) 5238-5242. doi: 10.1002/anie.201601672
28. [28]
  T. Tsuchiya, K. Terabe, M. Ochi, et al., ACS Nano 10 (2016) 1655-1661. doi: 10.1021/acsnano.5b07374
29. [29]
  T. Yamada, K. Morita, K. Kume, H. Yoshikawa, K. Awaga, J. Mater. Chem. C 2 (2014) 5183-5188. doi: 10.1039/C4TC00299G
30. [30]
  K. Taniguchi, K. Narushima, H. Sagayama, et al., Adv. Funct. Mater. 27 (2017) 1604990. doi: 10.1002/adfm.201604990
31. [31]
  M. Okubo, D. Asakura, Y. Mizuno, et al., Angew. Chem. Int. Ed. 50 (2011) 6269-6273. doi: 10.1002/anie.201102048
32. [32]
  Y. Mizuno, M. Okubo, K. Kagesawa, et al., Inorg. Chem. 51 (2012) 10311-10316. doi: 10.1021/ic301361h
33. [33]
  C.H. Li, M.K. Peprah, D. Asakura, et al., Chem. Mater. 27 (2015) 1524-1530. doi: 10.1021/cm503639a
34. [34]
  W. Antje, K. Heike, P.P. Irena, et al., Inorg. Chem. 41 (2002) 5706-5715. doi: 10.1021/ic0201654
35. [35]
  F.Q. Li, W. Zhang, A. Carné-Sánchez, et al., Inorg. Chem. 57 (2018) 8701-8704. doi: 10.1021/acs.inorgchem.8b00959
36. [36]
  W. Zhang, Y.Y. Zhao, V. Malgras, et al., Angew. Chem. Int. Ed. 55 (2016) 8228-8234. doi: 10.1002/anie.201600661
37. [37]
  Y.J. Fang, C.X. Chen, X.P. Ai, H.X. Yang, Y.L. Cao, Acta Phys-Chim. Sin. 33 (2017) 211-241.
38. [38]
  S. Liu, L.Y. Shao, X.J. Zhang, Z.L. Tao, J. Chen, Acta Phys.-Chim. Sin. 34 (2018) 581-597.
39. [39]
  Y. Mizuno, M. Okubo, E. Hosono, et al., J. Mater. Chem. A 1 (2013) 13055-13059. doi: 10.1039/c3ta13205f
40. [40]
  R.Y. Wang, B. Shyam, K.H. Stone, et al., Adv. Energy Mater. 5 (2015) 1401869. doi: 10.1002/aenm.201401869
41. [41]
  C.D. Wessells, R.A. Huggins, Y. Cui, Nat. Commun. 2 (2011) 550. doi: 10.1038/ncomms1563
42. [42]
  E. Reguera, J. Rodríguez-Hernández, A. Champi, et al., Z. Phys. Chem. 220 (2006) 1609-1619. doi: 10.1524/zpch.2006.220.12.1609
43. [43]
  D. Asakura, Y. Nanba, M. Okubo, et al., J. Phys. Chem. Lett. 5 (2014) 4008-4013. doi: 10.1021/jz501738m
44. [44]
  M. Verdaguer, G.S. Girolami, Magnetic prussian blue analogs, in: J.S. Miller, M. Dorillon (Eds.), Magnetism: Molecules to Materials V, Wiley-VCH, New York, 2005, pp. 283-346.
45. [45]
  T. Yamashita, P. Hayes, Appl. Surf. Sci. 254 (2008) 2441-2449. doi: 10.1016/j.apsusc.2007.09.063
46. [46]
  A. Lisowska-Oleksiak, M. Wilamowska, V. Jasulaitiené, Electrochim. Acta 56 (2011) 3626-3632. doi: 10.1016/j.electacta.2010.12.092
1. [1]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
2. [2]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654
3. [3]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
4. [4]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
5. [5]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
6. [6]
  Li Li , Zhi-Xin Yan , Chuan-Kun Ran , Yi Liu , Shuo Zhang , Tian-Yu Gao , Long-Fei Dai , Li-Li Liao , Jian-Heng Ye , Da-Gang Yu . Electro-reductive carboxylation of CCl bonds in unactivated alkyl chlorides and polyvinyl chloride with CO₂. Chinese Chemical Letters, 2024, 35(12): 110104-. doi: 10.1016/j.cclet.2024.110104
7. [7]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
8. [8]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
9. [9]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
10. [10]
  Yifei Cheng , Jiahui Yang , Wei Shao , Wanqun Zhang , Wanqun Hu , Weiwei Li , Kaiping Yang . Learning Goes Beyond the Written Word: Practical Insights from the “Leaf Electroplating” Popular Science Experiment. University Chemistry, 2024, 39(9): 319-327. doi: 10.3866/PKU.DXHX202310033
11. [11]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
12. [12]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
13. [13]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
14. [14]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
15. [15]
  Juanjuan Wang , Fang Wang , Bin Qin , Yue Wu , Huan Yang , Xiaolong Li , Lanfang Wang , Xiufang Qin , Xiaohong Xu . Controlled synthesis and excellent magnetism of ferrimagnetic NiFe₂Se₄ nanostructures. Chinese Chemical Letters, 2024, 35(11): 109449-. doi: 10.1016/j.cclet.2023.109449
16. [16]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
17. [17]
  Jiayao Li , Xinru Peng , Shiwei Yin , Changwei Wang , Yirong Mo . Metastability of π-π stacking between the closed-shell ions of like charges. Chinese Journal of Structural Chemistry, 2024, 43(5): 100213-100213. doi: 10.1016/j.cjsc.2023.100213
18. [18]
  Zhen Dai , Linzhi Tan , Yeyu Su , Kerui Zhao , Yushun Tian , Yu Liu , Tao Liu . Site-specific incorporation of reduction-controlled guest amino acids into proteins for cucurbituril recognition. Chinese Chemical Letters, 2024, 35(5): 109121-. doi: 10.1016/j.cclet.2023.109121
19. [19]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
20. [20]
  Jianmei Guo , Yupeng Zhao , Lei Ma , Yongtao Wang . Ultra-long room temperature phosphorescence, intrinsic mechanisms and application based on host-guest doping systems. Chinese Journal of Structural Chemistry, 2024, 43(9): 100335-100335. doi: 10.1016/j.cjsc.2023.100335

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(919)
HTML views(76)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142