Citation: Guan Xu, Wang Yan, Cai Wangfeng. A composite metal-organic framework material with high selective adsorption for dibenzothiophene[J]. Chinese Chemical Letters, ;2019, 30(6): 1310-1314. doi: 10.1016/j.cclet.2019.02.029 shu

A composite metal-organic framework material with high selective adsorption for dibenzothiophene

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

wfcai@tju.edu.cn

Received Date: 25 January 2019
Revised Date: 25 February 2019
Accepted Date: 26 February 2019
Available Online: 27 June 2019

Figures(3)

A copper-centred metal-organic framework material MOF-101 with 2-bromine terephthalic acid as ligands was synthesized by solvothermal method at 70℃ and modified by loading Ag⁺ to improve the selective adsorption performance. The MOF-101 and Ag⁺/MOF-101 prepared were characterised by powder X-ray diffraction, X-ray fluorescence, Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The adsorptive desulphurisation was quantified by adsorbing dibenzothiophene (DBT) from model oils. The loading of Ag⁺ enhanced the deep adsorptive desulfurization capacity for DBTand significantly weaken the adsorption competitiveness of toluene. As a result, the DBT concentration of model oil was reduced from 50 ppm_S to 10.2 ppm_S. Possible understandings were put forward to explain the adsorption performance of Ag⁺/MOF-101. The kinetics and isotherm data can be well-described by the pseudo-second-order kinetic model and the Langmuir model.
- Desulfurization,
- Adsorption,
- Metal-organic framework,
- Dibenzothiophene,
- Selective adsorption
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