Citation: Tian Shaokang, Shao Bowen, Wang Zhiqun, Li Shangda, Liu Xiangyu, Zhao Yibo, Li Lei. Organic ionic plastic crystal as electrolyte for lithium-oxygen batteries[J]. Chinese Chemical Letters, ;2019, 30(6): 1289-1292. doi: 10.1016/j.cclet.2019.02.027 shu

Organic ionic plastic crystal as electrolyte for lithium-oxygen batteries

Tian Shaokang ^a ,
Shao Bowen ^a ,
Wang Zhiqun ^a ,
Li Shangda ^a ,
Liu Xiangyu ^a ,
Zhao Yibo ^a ,
Li Lei ^a,b,*,

a.
School of Chemistry and Chemical Engineering, Shanghai Key Lab of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University, Shanghai 200240, China
b.
Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

lilei0323@sjtu.edu.cn

Received Date: 24 December 2018
Revised Date: 11 February 2019
Accepted Date: 26 February 2019
Available Online: 26 June 2019

Figures(4)

Organic ionic plastic crystals (OIPCs) composed of 1-ethyl-1-methyl pyrrolidinium bis(fluorosulfonyl) imide (P₁₂FSI) and lithium bis(fluorosulfonyl)imide (LiFSI) was used as electrolyte for lithium-oxygen batteries. Since P₁₂FSI-LiFSI electrolyte exhibited high ionic conductivity, good chemical stability and wide electrochemical window, the battery showed good rate capability, excellent cycling stability and can be operated stably for 320 cycles under a fixed capacity of 500 mAh/g_carbon. The use of OIPCs electrolyte could provide a new avenue for the development of high-performance Li-O₂ batteries.
- Organic ionic plastic crystal,
- Electrolyte,
- Lithium-oxygen batteries,
- Long life,
- Chemical stability
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