Citation: Shen Zhihao, Pi Chao, Cui Xiuling, Wu Yangjie. Rhodium(Ⅲ)-catalyzed intermolecular cyclization of anilines with sulfoxonium ylides toward indoles[J]. Chinese Chemical Letters, ;2019, 30(7): 1374-1378. doi: 10.1016/j.cclet.2019.01.033 shu

Rhodium(Ⅲ)-catalyzed intermolecular cyclization of anilines with sulfoxonium ylides toward indoles

Department of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, China

cuixl@hqu.edu.cn

wyj@zzu.edu.cn

Received Date: 3 January 2019
Revised Date: 21 January 2019
Accepted Date: 23 January 2019
Available Online: 3 July 2019

Figures(8)

Rhodium(Ⅲ)-catalyzed synthesis of indole derivatives has been realized via cascade reaction of C-H alkylation/nucleophilic cyclization starting from readily available N-phenylpyridin-2-amines and sulfoxonium ylides. Notably, this transformation could smoothly proceed with high yields, good regioselectivity, and feature broad group tolerance and under redox-neutral condition to avoid external oxidant. The titled products are potentially important building blocks in the organic synthesis through various chemical transformations.
- Rhodium,
- Cyclization,
- Aniline,
- Sulfoxonium ylide,
- Indole
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