Citation: Qiao Lizhen, Song Man, Geng Aifang, Yao Shuang. Polyoxometalate-based high-nuclear cobalt-vanadium-oxo cluster as efficient catalyst for visible light-driven CO₂ reduction[J]. Chinese Chemical Letters, ;2019, 30(6): 1273-1276. doi: 10.1016/j.cclet.2019.01.024 shu

Polyoxometalate-based high-nuclear cobalt-vanadium-oxo cluster as efficient catalyst for visible light-driven CO₂ reduction

Qiao Lizhen ^a,b,1 ,
Song Man ^a,b,1 ,
Geng Aifang ^a,*, ,
Yao Shuang ^a,b,*,

a.
School of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China
b.
School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China

E-mail addresses:

gengaf0687@sina.com

shuangyao@email.tjut.edu.cn

Received Date: 13 December 2018
Revised Date: 21 January 2019
Accepted Date: 22 January 2019
Available Online: 26 June 2019

Figures(4)

A high-nuclear Co-V-O cluster was firstly isolated by lacunary polyoxoanion, resulting in the high-nuclear mixed metal-oxo cluster-containing polyoxometalate (POM), K₄Na₂₈[{Co₄(O-H)₃(VO₄)}₄(SiW₉O₃₄)₄]·66H₂O (1). In 1, the {Co₄(O-H)₃(VO₄)}₄ {Co₁₆-V₄} core, composed of a {Co₄O₄} cubane, four {Co₄(OH)₃} qusi-cubanes and four VO₄ units, was stabilized by four lacunary A-α-{SiW₉O₃₄} units. Photocatalytic study reveals that 1 exhibits excellent photocatalytic activity for CO₂-to-CO conversion with high selectivity under visible light irradiation. The turnover number (TON) and turnover frequency (TOF) reaches as high as 10492 and 0.29 s^-1, respectively. Compound 1 represents the first high nuclear TM cluster-containing POM (TM=transition-metal) with efficient visible light catalytic activity for CO₂ reduction, and its photocatalytic activity is much higher than those of most reported molecular catalysts. Photoluminescence spectroscopy study reveals that photoexcitation of Ru-photosensitizer is followed by an efficient electron transfer to POMs to reduce CO₂.
- Polyoxometalate,
- High-nuclear cobalt cluster,
- Photocatalysis,
- CO₂ reduction,
- Photosensitizer
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沈阳化工大学材料科学与工程学院沈阳 110142

Polyoxometalate-based high-nuclear cobalt-vanadium-oxo cluster as efficient catalyst for visible light-driven CO2 reduction

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通讯作者: 陈斌, bchen63@163.com

Polyoxometalate-based high-nuclear cobalt-vanadium-oxo cluster as efficient catalyst for visible light-driven CO₂ reduction