Citation: Yu Xu, Pei Chengang, Feng Ligang. Surface modulated hierarchical graphene film via sulfur and phosphorus dual-doping for high performance flexible supercapacitors[J]. Chinese Chemical Letters, ;2019, 30(5): 1121-1125. doi: 10.1016/j.cclet.2019.01.009 shu

Surface modulated hierarchical graphene film via sulfur and phosphorus dual-doping for high performance flexible supercapacitors

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

ligang.feng@yzu.edu.cn

Received Date: 22 November 2018
Revised Date: 16 December 2018
Accepted Date: 10 January 2019
Available Online: 11 May 2019

Figures(4)

Graphene surface modification by heteroatom incorporation is an attractive strategy to construct flexible electrochemical capacitors. Herein, the steam-assistant heteroatoms of sulfur and phosphorus dualdoped graphene film (s-SPG) is fabricated via an ice-template and thermal-activation approach and they demonstrate an excellent pseudocapacitive behavior in flexible electrochemical capacitors. As probed by various microscopic and spectroscopic analysis, well-maintained porosity structure is formed during the freeze-drying and steam-activation treatment; the increased surface roughness is ascribed to heteroatoms doping by the formation of S- and P-containing functional groups as electrochemical active sites. A flexible device integrated by porous s-SPG film shows high pseudocapacitive behavior with high specific capacitance (169 F/g), rate capability (91.7%) and cyclic stability (92.5%). Even at the bend angle of 120°, no obvious change of specific capacitance is found indicating a good flexibility of s-SPG devices; the current study shows that s-SPG is a very promising electrode to realize the practical applications of all solid flexible supercapacitors.
- Heteroatom,
- Flexible devices,
- Steam-activation,
- Supercapacitor,
- Graphene film
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