Citation: Wang Chao, Wang Jing, Xiao Xiang, Zhong Guobin, Wu Shijia, Xu Kaiqi, Zhao Wei, Su Wei, Zeng Jie, Wu Baojun, Zhang Weili, Wu Changcheng, Shi Zhiqiang. Facile cyclic ammonium salt with the smallest size for high performance electric double layer capacitors[J]. Chinese Chemical Letters, ;2019, 30(6): 1269-1272. doi: 10.1016/j.cclet.2019.01.007 shu

Facile cyclic ammonium salt with the smallest size for high performance electric double layer capacitors

Wang Chao ^a ,
Wang Jing ^b,*, ,
Xiao Xiang ^a,*, ,
Zhong Guobin ^a ,
Wu Shijia ^a ,
Xu Kaiqi ^a ,
Zhao Wei ^a ,
Su Wei ^a ,
Zeng Jie ^a ,
Wu Baojun ^b ,
Zhang Weili ^b ,
Wu Changcheng ^b ,
Shi Zhiqiang ^b

a.
Electric Power Research Institute of Guangdong Power Grid Co., Ltd., Guangzhou 510080, China
b.
Tianjin Key Laboratory of Advanced Fibers and Energy Storage, College of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China

E-mail addresses:

wangjing@tjpu.edu.cn

xiaoxiang@gddky.csg.cn

Received Date: 8 November 2018
Revised Date: 28 December 2018
Accepted Date: 9 January 2019
Available Online: 9 June 2019

Figures(4)

The smallest cyclic ammonium salt reported to date, N, N-dimethylpyrrolidinium tetrafluoroborate (P₁₁-BF₄), was successively synthesized using a synthesis route without metal ions and halogen ions, then investigated as the electrolyte with Propylene carbonate in EDLCs. The electrochemical characteristics of EDLCs assembled by 1 mol/L P₁₁-BF₄/PC paired with activated carbon electrodes were compared to traditional electrolytes. P₁₁-BF₄ has proven to have superior voltage resistance by using cyclic voltammetry and constant current charge-discharge testing. Moreover, P₁₁-BF₄ exhibits a more brilliant rate performance due to its high conductivity. These results demonstrate that P₁₁-BF₄ is an ideal electrolyte to improve the energy density and power density of supercapacitors.
- N, N-Dimethylpyrrolidinium,
- tetrafluoroborate,
- Cyclic ammonium salt,
- Electrical conductivity,
- Supercapacitor,
- Rate performance
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沈阳化工大学材料科学与工程学院沈阳 110142