Citation: Wu Zhenghan, Si Tengda, Xu Guangqing, Xu Bin, Tang Wenjun. Ligand-free nickel-catalyzed Kumada couplings of aryl bromides with tert-butyl Grignard reagents[J]. Chinese Chemical Letters, ;2019, 30(3): 597-600. doi: 10.1016/j.cclet.2018.12.027 shu

Ligand-free nickel-catalyzed Kumada couplings of aryl bromides with tert-butyl Grignard reagents

Wu Zhenghan ^a ,
Si Tengda ^b ,
Xu Guangqing ^b ,
Xu Bin ^a,*, ,
Tang Wenjun ^b,*,

a.
Department of Chemistry, Shanghai University, Shanghai 200444, China
b.
State Key Laboratory of Bio-Organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

xubin@shu.edu.cn

tangwenjun@sioc.ac.cn

Received Date: 10 November 2018
Revised Date: 19 December 2018
Accepted Date: 24 December 2018
Available Online: 24 March 2018

Figures(5)

A ligand-free nickel-catalyzed Kumada cross-coupling of aryl bromides and tert-butyl Grignard reagents led to the formation of a series of tert-butyl aryls in moderate to good yields, excellent tBu/iBu ratios, and good functional group compatibility. A radical coupling process is indicated and a mechanism with a Ni(Ⅰ)-Ni(Ⅲ) catalytic cycle is proposed.
- Ligand free,
- Kumada cross-coupling,
- tert-Butyl arenes,
- Nickel catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142