Citation: Jin Yunxia, He Junjie, Ou Zaihua, Feng Chuanqi, Zhang Guangxue. Synthesis and electrochemical properties of Zn₃V₃O₈ as novel anode material[J]. Chinese Chemical Letters, ;2019, 30(3): 806-808. doi: 10.1016/j.cclet.2018.12.010 shu

Synthesis and electrochemical properties of Zn₃V₃O₈ as novel anode material

Jin Yunxia ^a ,
He Junjie ^a ,
Ou Zaihua ^c ,
Feng Chuanqi ^a,b,*, ,
Zhang Guangxue ^b,**,

a.
Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials & Ministry of Education Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University, Wuhan 430062, China
b.
School of Nuclear Technology and Chemistry & Biology, Hubei University of Science and Technology, Xianning 437100, China
c.
Nanxian Fanggu Middle School, Yiyang 413211, China

^**

cfeng@hubu.edu.cn

zgx@hbust.edu.edu.cn

Received Date: 22 November 2018
Revised Date: 5 December 2018
Accepted Date: 7 December 2018
Available Online: 8 March 2018

Figures(3)

Zn₃V₃O₈ two-dimensional micro sheets are successfully synthesized by combination of solvothermal method and heat treatment. The X-ray diffraction (XRD) and field emission scanning electron microscopy (SEM) are used to characterize the structure and morphology of the samples, and the battery testing system is used to investigate its electrochemical performance. The results show that the Zn₃V₃O₈ is successfully obtained using mix solvent (water:ethylene glycol=1:1), and the sample takes on morphology of two-dimensional sheets. The initial discharge capacity for Zn₃V₃O₈ two-dimensional micro sheets is 752.0 mAh/g at 100 mA/g in the voltage range of 0.01-3 V. After heat treatment in a tube furnace at 550℃, the sample had the initial discharge capacity as 1152.0 mAh/g and maintained it at 901.4 mAh/g after 100 cycles. The good electrochemical performance for Zn₃V₃O₈ two-dimensional micro sheets make it possible to be used as novel anode for lithium ion battery application.
- Inorganic compound,
- Inorganic synthesis,
- Electronic materials,
- Anode material,
- Zn₃V₃O₈
1. [1]
  V. Etacheri, R. Marom, R. Elazari, G. Salitra, D. Aurbach, Energy Environ. Sci. 4(2011) 324-3262.
2. [2]
  L.H. Gan, D. Deng, Y. Zhang, et al., J. Mater. Chem. A-Mater. Energy Sustain. 2(2014) 2461-2466. doi: 10.1039/c3ta14242f
3. [3]
  N. Yan, Y. Xu, H.J. Li, W. Chen, Mater. Lett. 165(2016) 223-226. doi: 10.1016/j.matlet.2015.11.061
4. [4]
  M. Armand, J.M. Tarascon, Nature 541(2008) 652-657.
5. [5]
  J.B. Goodenough, Y. Kim, Chem. Mater. 22(2010) 587-603. doi: 10.1021/cm901452z
6. [6]
  X.L. Liu, Y.C. Cao, H. Zheng, X. Chen, C.Q. Feng, Appl. Surf. Sci. 394(2017) 183-189. doi: 10.1016/j.apsusc.2016.09.133
7. [7]
  X.L. Liu, Y.C. Cao, H. Zheng, C.Q. Feng, Mater. Lett. 187(2017) 15-19. doi: 10.1016/j.matlet.2016.10.022
8. [8]
  T. Zhang, H. Wu, S. Wang, et al., Mater. Lett. 225(2018) 69-72. doi: 10.1016/j.matlet.2018.04.081
9. [9]
  J. He, X. Liu, X. Chen, H. Zheng, C. Feng, J. Alloy Comp. 741(2018) 315-322. doi: 10.1016/j.jallcom.2017.10.209
10. [10]
  P.C. Liu, K.J. Zhu, Y.N. Gao, H.J. Luo, L. Lu, Adv. Energy Mater. 7(2017) 1700547-1700571. doi: 10.1002/aenm.v7.23
11. [11]
  R. Nie, G. Fang, J. Zhou, et al., Electrochim. Acta 246(2017) 97-105. doi: 10.1016/j.electacta.2017.06.044
12. [12]
  L.B. Ma, T. Chen, G.Y. Zhu, et al., J. Mater. Chem. A-Mater. Energy Sustain. 4(2016) 15041-15048. doi: 10.1039/C6TA06692E
13. [13]
  T. Morishita, K. Homura, T. Inamasu, M. Inagaki, Solid State Ionics 177(2006) 1347-1353. doi: 10.1016/j.ssi.2006.05.035
14. [14]
  G.Q. Zhang, L. Yu, H.B. Wu, H.E. Hoster, X. Lou, Adv. Mater. 24(2012) 4609-4613. doi: 10.1002/adma.v24.34
15. [15]
  G.Y. Zhu, L. Wang, H.N. Lin, et al., Adv. Funct. Mater. 28(2018) 1800003-1800010. doi: 10.1002/adfm.v28.18
16. [16]
  T. Chen, Y. Hu, B.R. Cheng, et al., Nano Energy 20(2016) 305-314. doi: 10.1016/j.nanoen.2015.12.024
17. [17]
  P.P. Sun, X.Y. Zhao, R.P. Chen, et al., Nanoscale 8(2016) 7408-7415. doi: 10.1039/C5NR08832A
1. [1]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
2. [2]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
3. [3]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
4. [4]
  Shuo Zhang , Haitao Liao , Zhi-Qun Liu , Chong Yan , Jia-Qi Huang . Re-evaluating the nano-sized inorganic protective layer on Cu current collector for anode free lithium metal batteries. Chinese Chemical Letters, 2024, 35(7): 109284-. doi: 10.1016/j.cclet.2023.109284
5. [5]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
6. [6]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
7. [7]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
8. [8]
  Yan Cheng , Hai-Quan Yao , Ya-Di Zhang , Chao Shi , Heng-Yun Ye , Na Wang . Nitrate-bridged hybrid organic-inorganic perovskites. Chinese Journal of Structural Chemistry, 2024, 43(9): 100358-100358. doi: 10.1016/j.cjsc.2024.100358
9. [9]
  Chuang LIU , Lichao SUN , Qingfeng ZHANG . Chiral inorganic nanocatalysts for electrochemical and enzyme-mimicked biosensing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 59-78. doi: 10.11862/CJIC.20240406
10. [10]
  Chong Liu , Nanthi Bolan , Anushka Upamali Rajapaksha , Hailong Wang , Paramasivan Balasubramanian , Pengyan Zhang , Xuan Cuong Nguyen , Fayong Li . Critical review of biochar for the removal of emerging inorganic pollutants from wastewater. Chinese Chemical Letters, 2025, 36(2): 109960-. doi: 10.1016/j.cclet.2024.109960
11. [11]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
12. [12]
  Haijiao Liu , Qiao Feng , Yu Huang , Feng Wu , Yali Liu , Minxia Shen , Xiao Guo , Wenting Dai , Weining Qi , Yifan Zhang , Lu Li , Qiyuan Wang , Bianhong Zhou , Jianjun Li . Composition and size distribution of wintertime inorganic aerosols at ground and alpine regions of northwest China. Chinese Chemical Letters, 2024, 35(11): 109636-. doi: 10.1016/j.cclet.2024.109636
13. [13]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
14. [14]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
15. [15]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
16. [16]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
17. [17]
  Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
18. [18]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
19. [19]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
20. [20]
  Xinyu Tian , Jiaxiang Guo , Zeyi Li , Shihou Sheng , Tianyu Zhang , Xianfei Li , Chuandong Dou . Control over electronic structures of organic diradicaloids via precise B/O-heterocycle fusion. Chinese Chemical Letters, 2025, 36(1): 110174-. doi: 10.1016/j.cclet.2024.110174

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(658)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and electrochemical properties of Zn3V3O8 as novel anode material

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and electrochemical properties of Zn₃V₃O₈ as novel anode material