Citation: Wang Xia, Fan Weidong, Zhang Ming, Shang Yizhu, Wang Yutong, Liu Di, Guo Hailing, Dai Fangna, Sun Daofeng. Ligand controlled structure of cadmium(Ⅱ) metal-organic frameworks for fluorescence sensing of Fe³⁺ ion and nitroaromatic compounds[J]. Chinese Chemical Letters, ;2019, 30(3): 801-805. doi: 10.1016/j.cclet.2018.12.009 shu

Ligand controlled structure of cadmium(Ⅱ) metal-organic frameworks for fluorescence sensing of Fe³⁺ ion and nitroaromatic compounds

Wang Xia ^a,1 ,
Fan Weidong ^a,1 ,
Zhang Ming ^a ,
Shang Yizhu ^a ,
Wang Yutong ^a ,
Liu Di ^b ,
Guo Hailing ^c ,
Dai Fangna ^a,*, ,
Sun Daofeng ^a

a.
School of Materials Science and Engineering, College of Science, China University of Petroleum (East China), Qingdao 266580, China
b.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
c.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, China

fndai@upc.edu.cn

Received Date: 18 September 2018
Revised Date: 1 November 2018
Accepted Date: 6 December 2018
Available Online: 7 March 2018

Figures(7)

Three cadmium(Ⅱ) metal-organic frameworks (MOFs) based on tetracarboxylate ligands, namely [Cd₂(TTTA)(DMF)₃] 2DMF (1), [Cd₂(TB)(H₂O)₄] 3DMF H₂O (2) and [Cd(TEB)_0.5] 2DMF 4H₂O (3) have been designed and synthesized. Complex 1 is a 2-dimensional (2D) 3, 4-connected network with 3, 4L13 topology, complex 2 features a 3-dimensional (3D) 3, 4-connected tfa topology with a 2-fold interpenetrating structure and complex 3 has a 3D 4-connected dia topology with a 4-fold interpenetrating structure. Interestingly, 2 exhibits permanent pores and selective adsorption of CO₂ over CH₄. In addition, 2 shows fluorescence sensing of Fe³⁺ ion and rapid detection of nitroaromatic compounds (NACs) through fluorescence quenching.
- Metal-organic frameworks,
- Selective adsorption,
- Fluorescence sensing,
- Fe³⁺ ion,
- Nitroaromatic compounds
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沈阳化工大学材料科学与工程学院沈阳 110142

Ligand controlled structure of cadmium(Ⅱ) metal-organic frameworks for fluorescence sensing of Fe3+ ion and nitroaromatic compounds

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通讯作者: 陈斌, bchen63@163.com

Ligand controlled structure of cadmium(Ⅱ) metal-organic frameworks for fluorescence sensing of Fe³⁺ ion and nitroaromatic compounds