Citation: Liu Bin, Zhou Xigeng. Synthesis of 1, 2-phenylenedimethanols by base-promoted reduction of isobenzofuran-1(3H)-ones with silane[J]. Chinese Chemical Letters, ;2019, 30(3): 725-728. doi: 10.1016/j.cclet.2018.11.025 shu

Synthesis of 1, 2-phenylenedimethanols by base-promoted reduction of isobenzofuran-1(3H)-ones with silane

Liu Bin ^a,b ,
Zhou Xigeng ^a,*,

a.
Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
b.
Technology Research Insititute of Shanghai Huayi (Group) Company, Shanghai 200241, China

xgzhou@fudan.edu.cn

Received Date: 22 October 2018
Revised Date: 10 November 2018
Accepted Date: 19 November 2018
Available Online: 20 March 2018

Figures(3)

An efficient method for preparation of substituted 1, 2-phenylenedimethanols and aliphatic 1, 4-diols that are valuable intermediates in organic synthesis, has been developed by the base-promoted reduction of isobenzofuran-1(3H)-ones and γ-lactones with silane under mild conditions. Compared with traditional procedures using stoichiometric amounts of metal hydrides and alkyl reductants, the present method avoids the use of sensitive reagents and is operationally simple and a broad variety of functional groups are tolerated.
- Isobenzofuran-1(3H)-one,
- 1, 2-Phenylenedimethanol,
- Reductive transformation,
- Ring-opening reaction,
- Silane
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