Citation: Li Yan, Li Mengqi, Zhang Jie, Xu Xiaoyan. Adsorption properties of the double-imprinted electrospun crosslinked chitosan nanofibers[J]. Chinese Chemical Letters, ;2019, 30(3): 762-766. doi: 10.1016/j.cclet.2018.11.005 shu

Adsorption properties of the double-imprinted electrospun crosslinked chitosan nanofibers

Li Yan ^a,b,*, ,
Li Mengqi ^a ,
Zhang Jie ^a ,
Xu Xiaoyan ^a

a.
School of Materials Science and Engineering, Tongji University, Shanghai 200092, China
b.
Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

yanl@tongji.edu.cn

Received Date: 10 October 2018
Revised Date: 26 October 2018
Accepted Date: 1 November 2018
Available Online: 9 March 2018

Figures(7)

The adsorption properties of the Pb(Ⅱ)-Cd(Ⅱ) double-imprinted electrospun crosslinked chitosan nanofibers (Pd/Cd-DIECCNs) prepared by electropspinning and imprinting process for the removal of Pb (Ⅱ) and Cd(Ⅱ) from aqueous solutions were investigated. The prepared nanofibers were characterized by scanning electron microscope (SEM) analysis. Under the optimum experimental conditions, the minimum fiber average diameter was obtained 110 nm. Then the adsorption experiments were carried out to study the effect of different adsorption parameters, such as pH, the ratio between Pb(Ⅱ) and Cd(Ⅱ) in the mixed solutions, contact time, the Pd/Cd-DIECCNs dose and temperature in a batch system. The Extended Langmuir model was applied to describe the equilibrium data of Pb(Ⅱ) and Cd(Ⅱ). The maximum adsorption capacities of the Pd/Cd-DIECCNs arrived at 567 mg/g for Pb(Ⅱ) and 341 mg/g for Cd (Ⅱ), respectively.
- Chitosan,
- Double imprinted,
- Crosslinked,
- Electrospun,
- Adsorption
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