Citation: Chen Shengrui, Liang Jiyuan, Zhao Jinxing, Li Haifeng, Liu Yan, Deng Heming, Liu Chang, Tang Shun, Cao Yuan-Cheng. Preparation of nitrogen doped clews-like carbon materials and their application as the electrode in supercapacitor[J]. Chinese Chemical Letters, ;2019, 30(3): 787-791. doi: 10.1016/j.cclet.2018.11.003 shu

Preparation of nitrogen doped clews-like carbon materials and their application as the electrode in supercapacitor

Chen Shengrui ^a ,
Liang Jiyuan ^a,*, ,
Zhao Jinxing ^a ,
Li Haifeng ^a ,
Liu Yan ^a ,
Deng Heming ^c ,
Liu Chang ^a ,
Tang Shun ^a ,
Cao Yuan-Cheng ^b,*,

a.
Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, Jianghan University, Wuhan 430056, China
b.
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
c.
State Grid Electric Power Research Institute, Wuhan 430074, China

liangjy2004@126.com

yccao@hust.edu.cn

Received Date: 6 October 2018
Revised Date: 2 November 2018
Accepted Date: 5 November 2018
Available Online: 7 March 2018

Figures(5)

In this work, nitrogen doped clews-like carbon materials were successfully fabricated through hydrothermal polymerization method, followed by post treatment that integrated the carbonization, activation and post-nitrogen doping into one process. This preparation method can form particular hierarchical porous structure without using any sacrificial templates. The experimental results show that the nitrogen doped clews-like hierarchical porous carbon materials possess a relatively high specific surface area of 815 m²/g with the nitrogen content of 10.58 at%. The electrochemical properties show that the resulting sample delivers 258 F/g at a 0.5 A/g and excellent capacity retention of 79% at 20 A/g. After conducting 10, 000 charge-discharge cycles at 10 A/g, the capacitance retention of 98.3% is achieved. These intriguing results demonstrate that the obtained nitrogen doped clews-like carbon materials will be promising electrode materials for supercapacitor and other energy storage devices.
- Porous carbon material,
- Nitrogen doped,
- Clews-like,
- Hierarchical,
- Electrode
1. [1]
  R. Dai, W. Sun, Y. Wang, Electrochim. Acta 217(2016) 123-131. doi: 10.1016/j.electacta.2016.08.051
2. [2]
  M. Xie, S. Duan, Y. Shen, et al., ACS Energy Lett. 1(2016) 814-819. doi: 10.1021/acsenergylett.6b00258
3. [3]
  C. Long, L. Jiang, X. Wu, et al., Carbon 93(2015) 412-420. doi: 10.1016/j.carbon.2015.05.040
4. [4]
  K. Xiang, Z. Xu, T. Qu, et al., Chem. Commun. 53(2017) 12410-12413. doi: 10.1039/C7CC07515D
5. [5]
  M. Xie, Z. Xu, S. Duan, et al., Nano Res. 11(2018) 216-224. doi: 10.1007/s12274-017-1621-4
6. [6]
  Z.F. Tian, M.J. Xie, Y. Shen, et al., Chin. Chem. Lett. 28(2017) 863-867. doi: 10.1016/j.cclet.2016.12.004
7. [7]
  M. Sevilla, R. Mokaya, Energy Environ. Sci. 7(2014) 1250-1280. doi: 10.1039/C3EE43525C
8. [8]
  J. Liang, T. Qu, X. Kun, et al., Appl. Surf. Sci. 436(2018) 934-940. doi: 10.1016/j.apsusc.2017.12.142
9. [9]
  J. Tian, C. Cui, C. Zheng, W. Qian, Chin. Chem. Lett. 29(2018) 599-602. doi: 10.1016/j.cclet.2018.01.027
10. [10]
  J. Wei, D. Zhou, Z. Sun, et al., Adv. Funct. Mater. 23(2013) 2322-2328. doi: 10.1002/adfm.201202764
11. [11]
  W.J. Lu, S.Z. Huang, L. Miao, et al., Chin. Chem. Lett. 28(2017) 1324-1329. doi: 10.1016/j.cclet.2017.04.007
12. [12]
  B. Li, F. Dai, Q. Xiao, et al., Energy Environ. Sci. 9(2015) 102-106.
13. [13]
  Y. Zhang, T. Qu, K. Xing, et al., J. Mater. Chem. A 6(2018) 2353-2359. doi: 10.1039/C7TA09644E
14. [14]
  Z.S. Wu, K. Parvez, A. Winter, et al., Adv. Mater. 26(2014) 4552-4558. doi: 10.1002/adma.v26.26
15. [15]
  T.C. Chou, R.A. Doong, C.C. Hu, et al., ChemSusChem 7(2014) 841-847. doi: 10.1002/cssc.201301014
16. [16]
  L. Xie, G. Sun, F. Su, et al., J. Mater. Chem. A 4(2016) 1637-1646. doi: 10.1039/C5TA09043A
17. [17]
  Q. Wang, J. Yan, Y. Wang, et al., Carbon 67(2014) 119-127. doi: 10.1016/j.carbon.2013.09.070
18. [18]
  J. Zhou, Z. Zhang, W. Xing, et al., Electrochim. Acta 153(2015) 68-75. doi: 10.1016/j.electacta.2014.11.075
19. [19]
  J. Liang, J. Zhao, Y. Li, et al., J. Taiwan Inst. Chem. E 81(2017) 383-390. doi: 10.1016/j.jtice.2017.10.001
20. [20]
  S.S. Yang, M.J. Xie, Y. Shen, et al., Chin. Chem. Lett. 27(2016) 507-510. doi: 10.1016/j.cclet.2016.01.058
21. [21]
  Z. Lyu, D. Xu, L. Yang, et al., Nano Energy 12(2015) 657-665. doi: 10.1016/j.nanoen.2015.01.033
22. [22]
  X. Zhang, L. Ma, M.Y. Gan, et al., J. Power Sources 304(2017) 22-31.
23. [23]
  H. Peng, J. Liang, L. Zhu, et al., ACS Nano 8(2014) 11280-11289. doi: 10.1021/nn503985s
24. [24]
  S. Zeng, N. Jin, H. Zhang, et al., RSC Adv. 4(2014) 18676-18682. doi: 10.1039/C4RA01313A
25. [25]
  S. Zeng, X. Zeng, W. Tu, et al., J. Mater. Chem. A 5(2017) 23209-23220. doi: 10.1039/C7TA08520F
26. [26]
  W.D. Oh, G. Lisak, R.D. Webster, et al., Appl. Catal. B:Environ. 233(2018) 120-129. doi: 10.1016/j.apcatb.2018.03.106
27. [27]
  J. Zhao, C. Liu, H. Deng, et al., Mater. Today Energy 8(2018) 134-142. doi: 10.1016/j.mtener.2018.03.007
28. [28]
  Z. Lin, G. Waller, Y. Liu, et al., Adv. Energy Mater. 2(2012) 884-888. doi: 10.1002/aenm.201200038
29. [29]
  D. Xie, X. Xia, Y. Zhong, et al., Adv. Energy Mater. 7(2017) 1601804. doi: 10.1002/aenm.201601804
30. [30]
  K. Mi, S. Chen, B. Xi, et al., Adv. Funct. Mater. 27(2017) 1604265. doi: 10.1002/adfm.v27.1
31. [31]
  J. Yang, Z. Ju, Y. Jiang, et al., Adv. Mater. 30(2018) 1700104. doi: 10.1002/adma.v30.4
32. [32]
  Y. Li, Z. Wang, L. Lin, et al., Carbon 99(2016) 556-563. doi: 10.1016/j.carbon.2015.12.066
33. [33]
  L. Lai, Y. Zhao, S. Ying, et al., RSC Adv. 8(2018) 18714-18722. doi: 10.1039/C8RA02110D
34. [34]
  Y. Zhang, F. Wang, H. Zhu, et al., Appl. Surf. Sci. 426(2017) 99-106. doi: 10.1016/j.apsusc.2017.07.127
35. [35]
  W. Xing, S. Qiao, R. Ding, et al., Carbon 44(2006) 216-224. doi: 10.1016/j.carbon.2005.07.029
36. [36]
  J.Y. Liang, C.C. Wang, S.Y. Lu, J. Mater. Chem. A 3(2015) 24453-24462. doi: 10.1039/C5TA08007J
37. [37]
  M. Xie, J. Yang, J. Liang, X. Guo, W. Ding, Carbon 77(2014) 215-225. doi: 10.1016/j.carbon.2014.05.024
1. [1]
  Lanfang Wang , Jiangnan Lv , Yujia Li , Yanqing Hao , Wenjiao Liu , Hui Zhang , Xiaohong Xu . One-step synthesis of nanowoven ball-like NiS-WS₂ for high-efficiency hydrogen evolution. Chinese Chemical Letters, 2025, 36(1): 109597-. doi: 10.1016/j.cclet.2024.109597
2. [2]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
3. [3]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
4. [4]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
5. [5]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
6. [6]
  Chao-Long Chen , Rong Chen , La-Sheng Long , Lan-Sun Zheng , Xiang-Jian Kong . Anchoring heterometallic cluster on P-doped carbon nitride for efficient photocatalytic nitrogen fixation in water and air ambient. Chinese Chemical Letters, 2024, 35(4): 108795-. doi: 10.1016/j.cclet.2023.108795
7. [7]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
8. [8]
  Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang . Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts. Chinese Chemical Letters, 2025, 36(2): 110439-. doi: 10.1016/j.cclet.2024.110439
9. [9]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
10. [10]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
11. [11]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2024.100199
12. [12]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
13. [13]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
14. [14]
  Xiaxia Xing , Xiaoyu Chen , Zhenxu Li , Xinhua Zhao , Yingying Tian , Xiaoyan Lang , Dachi Yang . Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication. Chinese Chemical Letters, 2024, 35(9): 109230-. doi: 10.1016/j.cclet.2023.109230
15. [15]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
16. [16]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
17. [17]
  Yi Zhou , Yanzhen Liu , Yani Yan , Zonglin Yi , Yongfeng Li , Cheng-Meng Chen . Enhanced oxygen reduction reaction on La-Fe bimetal in porous N-doped carbon dodecahedra with CNTs wrapping. Chinese Chemical Letters, 2025, 36(1): 109569-. doi: 10.1016/j.cclet.2024.109569
18. [18]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
19. [19]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
20. [20]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(694)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142