Citation: Zheng Si-Tai, Yin Huan-Huan, Ma Zhao-Guang, Sheng Nan-Li, Zhan Tian-Guang, Yan Xiao-Yang, Cui Jiecheng, Liu Li-Juan, Zhang Kang-Da. Low-molecular-weight photoresponsive supramulecular hydrogel based on a dicationic azobenzene-bridged pyridinium hydrogelator[J]. Chinese Chemical Letters, ;2019, 30(3): 707-709. doi: 10.1016/j.cclet.2018.10.024 shu

Low-molecular-weight photoresponsive supramulecular hydrogel based on a dicationic azobenzene-bridged pyridinium hydrogelator

a.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, China
b.
Xingzhi College of Zhejiang Normal University, Jinhua 321004, China

tgzhan@zjnu.cn

kangda.zhang@zjnu.cn

Received Date: 31 July 2018
Revised Date: 19 October 2018
Accepted Date: 22 October 2018
Available Online: 25 March 2018

Figures(5)

Low-molecular-weight supramolecular hydrogels are of significant attractive soft materials as particular functions can be facilely introduced by the straightforward fabrication of such self-assembled systems. In this study, an azobenzene-bridged dicationic pyridinium salt was synthesized, from which photoresponsive supramolecular hydrogel could be fabricated through the π-π stacking and hydrophobic interactions in the aqueous solution. By taking advantages of the UV-vis light induced E/Z photoisomerization behaviors of the incorporated azobenzene photochromophore, reversible gel-sol transformation of such supramolecular hydrogel could be achieved under the alternating UV-vis irradiation conditions. We believed that this photoresponsive supramolecular hydrogel will be a good supplementary in the creation of intelligent soft material.
- Supramolecular self-assembly,
- Hydrogels,
- Photo-responsiveness,
- Azobenzenes,
- Smart soft materials
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1.
沈阳化工大学材料科学与工程学院沈阳 110142