Citation: Zhang Kunlei, Dai Kun, Bai Ruyan, Ma Yuchan, Deng Yan, Li Delei, Zhang Xi, Hu Rong, Yang Yunhui. A competitive microcystin-LR immunosensor based on Au NPs@metal-organic framework (MIL-101)[J]. Chinese Chemical Letters, ;2019, 30(3): 664-667. doi: 10.1016/j.cclet.2018.10.021 shu

A competitive microcystin-LR immunosensor based on Au NPs@metal-organic framework (MIL-101)

College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China

hudierong_168@163.com

yyhui2002@aliyun.com

Received Date: 4 August 2018
Revised Date: 18 October 2018
Accepted Date: 19 October 2018
Available Online: 23 March 2018

Figures(4)

An electrochemical immunosensor was developed for ultrasensitive detection of microcystin-LR in water. MIL-101, a porous metal-organic frameworks (MOFs) material based on trivalent chromium skeleton were synthesized by hydrothermal synthesis method, and loaded with Au nanoparticles (Au NPs) to prepare Au NPs@MIL-101 composite materials which were used as a marker to label anti microcystin-LR (Anti-MC-LR). The composite materials have strong catalytic properties to the oxidation of ascorbic acid. Anti-MC-LR was immobilized on glassy carbon electrode surface using electrodeposition graphene oxide (GO) as an immobilization matrix to construct a competitive microcystin-LR immunosensor. The electrochemical immunosensor display linear relationship in the range of 0.05 ng/mL-75 μg/mL with linear correlation coefficient of 0.9951 and detection limit of 0.02 ng/mL (S/N=3). This sensor was used to detect microcystin-LR in the water sample. The recovery was 102.43%, which is satisfied. The good testing results indicate the sensor has a great prospect in practical application.
- Microcystin-LR,
- Metal-organic frameworks,
- MIL-101,
- Competitive,
- Electrochemical immunosensor
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