Citation: Zhao Shaofei, Zeng Lizhen, Cheng Gao, Yu Lin, Zeng Huaqiang. Ni/Co-based metal-organic frameworks as electrode material for high performance supercapacitors[J]. Chinese Chemical Letters, ;2019, 30(3): 605-609. doi: 10.1016/j.cclet.2018.10.018 shu

Ni/Co-based metal-organic frameworks as electrode material for high performance supercapacitors

Zhao Shaofei ^a ,
Zeng Lizhen ^b ,
Cheng Gao ^a ,
Yu Lin ^a,*, ,
Zeng Huaqiang ^c,*,

a.
School of Chemical Engineering & Light Industry, Guangdong University of Technology, Guangzhou 510006, China
b.
Analysis and Testing Center, South China Normal University, Guangzhou 510006, China
c.
Institute of Bioengineering and Nanotechnology, Singapore 138669, Singapore

gychgdut@126.com

hqzeng@ibn.a-star.edu.sg

Received Date: 19 July 2018
Revised Date: 30 September 2018
Accepted Date: 17 October 2018
Available Online: 28 March 2018

Figures(4)

A novel bimetallic Ni/Co-based metal-organic framework (Ni/Co-MOF) was successfully synthesized via a simple solvothermal method, and used as electrode material for high performance supercapacitors. After doping of Co element, the Ni/Co-MOF materials retain the original crystalline topology structure of Ni₃(BTC)₂·12H₂O. The as-obtained Ni/Co-MOF demonstrates an excellent specific capacitance of 1067 and 780 F/g at current density of 1 and 10 A/g, respectively, and can also retain 68.4% of the original capacitance after 2500 cycles. These results suggest that bimetallic Ni/Co-based MOFs are promising materials for the next generation supercapacitance, owing to their excellent electrochemical performance. The synthetic procedure can be applied to synthesize other bimetallic MOFs and enhance their conductive property.
- Metal-organic frameworks,
- Bimetallic,
- Supercapacitance,
- Ni/Co,
- Synergistic effect
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