Citation: Kong Xingang, Zhang Jiarui, Huang Jianfeng, Li Jiayin, Qin Yi, Zhao Ting, Feng Qi. Microwave assisted hydrothermal synthesis of tin niobates nanosheets with high cycle stability as lithium-ion battery anodes[J]. Chinese Chemical Letters, ;2019, 30(3): 771-774. doi: 10.1016/j.cclet.2018.10.006 shu

Microwave assisted hydrothermal synthesis of tin niobates nanosheets with high cycle stability as lithium-ion battery anodes

Kong Xingang ^a,*, ,
Zhang Jiarui ^a ,
Huang Jianfeng ^a ,
Li Jiayin ^a ,
Qin Yi ^a ,
Zhao Ting ^a ,
Feng Qi ^a,b,*,

a.
School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
b.
Department of Advanced Materials Science, Faculty of Engineering, Kagawa University, Takamatsu-shi 761-0396, Japan

yezhu_1983@163.com

feng@eng.kagawa-u.ac.jp

Received Date: 2 August 2018
Revised Date: 30 September 2018
Accepted Date: 9 October 2018
Available Online: 12 March 2018

Figures(3)

In this study, SnNb₂O₆ and Sn₂Nb₂O₇ nanosheets are synthetized via microwave assisted hydrothermal method, and innovatively employed as anode materials for lithium-ion battery. The SnNb₂O₆ electrode exhibits high reversible capacity and excellent cycling stability (498 mAh/g at 0.1 A/g after 100 cycles), which is superior to that of Sn₂Nb₂O₇ electrode (173 mAh/g at 0.1 A/g after 100 cycles). Even increasing the current density to 2.0 A/g, the SnNb₂O₆ electrode still delivers a reversible capacity up to 306 mA h/g. The rate performance of the SnNb₂O₆ electrode is also better than that of Sn₂Nb₂O₇ electrode at different current densities from 0.1 A/g to 2.0 A/g. The enhanced electrochemical performance of SnNb₂O₆ nanosheets can be attributed to the unique layered structure, which is conducive to the diffusion of the lithium ions and the migration of electrons during discharge/charge.
- Tin niobates nanosheets,
- Microwave assisted hydrothermal,
- Anode materials,
- Lithium ion batteries,
- Layered structure
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