Citation: Liu Lili, Du Changjiang, Wang Shili, Chen Shimou. Three new bifunctional additive for safer nickel-cobalt-aluminum based lithium ion batteries[J]. Chinese Chemical Letters, ;2018, 29(12): 1781-1784. doi: 10.1016/j.cclet.2018.10.002 shu

Three new bifunctional additive for safer nickel-cobalt-aluminum based lithium ion batteries

a.
School of Sciences/Key Laboratory of Cosmetic, China National Light Industry, Beijing Technology and Business University, Beijing 100048, China
b.
Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

chenshimou@ipe.ac.cn

Received Date: 17 July 2018
Revised Date: 21 August 2018
Accepted Date: 27 August 2018
Available Online: 11 December 2018

Figures(4)

Three different types of new electrolyte additives were adopted as flame retardant to improve the safety of nickel-cobalt-aluminum (LiNi_0.8Co_0.15Al_0.05O₂, abbreviation NCA) based lithium batteries. By adding 5 wt% of the additives, an obvious flame retardant effect can be observed for the electrolyte. Furthermore, it was found that the additives can help for forming a stable cathode electrolyte interface (CEI) film on the NCA cathode, which are important for enhancing the thermal stability of the electrolyte and make the electrolyte obviously reduce the flammability, as well as good effect on the cycling cycle performance of the battery. These results indicate that our flame retardant are favorable additives in conventional liquid electrolytes for rechargeable lithium-ion batteries with good safety and high performances.
- Lithium ion batteries,
- Electrolyte,
- Flame retardant additives,
- Film-forming additives,
- NCA
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1.
沈阳化工大学材料科学与工程学院沈阳 110142