Citation: Wang Yaoyao, Shen Jun, Chen Qun, Wang Liang, He Mingyang. Nickel-catalysed C-O bond reduction of 2, 4, 6-triaryloxy-1, 3, 5-triazines in 2-methyltetrahydrofuran[J]. Chinese Chemical Letters, ;2019, 30(2): 409-412. doi: 10.1016/j.cclet.2018.09.009 shu

Nickel-catalysed C-O bond reduction of 2, 4, 6-triaryloxy-1, 3, 5-triazines in 2-methyltetrahydrofuran

School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Changzhou University, Changzhou 213164, China

liangwang@cczu.edu.cn

hmy@cczu.edu.cn

Received Date: 8 June 2018
Revised Date: 3 September 2018
Accepted Date: 10 September 2018
Available Online: 12 February 2018

Figures(7)

A nickel-catalysed reduction of phenol derivatives activated by 2, 4, 6-trichloro-1, 3, 5-triazine (TCT) in ecofriendly 2-methyltetrahydrofuran (2-MeTHF) is described. The phenol-TCT derivatives were readily prepared using grinding method in short time without further purification. This catalytic system allowed the facile C-O cleavage of phenol-TCT derivatives under mild reaction conditions with high efficiency and good functional group tolerance. Gram-scale reaction was also achieved. Particularly, sequential functionalization of phenol-TCT derivatives followed by C-O bond reduction could also be realized, affording the high value-added products in moderate to good yields.
- Nickel catalysis,
- Phenol derivatives,
- C-O bond cleavage,
- Green solvent
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