Citation: Wang Fei, Wei Tian-Qi, Xu Pei, Wang Shun-Yi, Ji Shun-Jun. Mn(Ⅲ)-mediated radical cascade reaction of boronic acids with isocyanides: Synthesis of diimide derivatives[J]. Chinese Chemical Letters, ;2019, 30(2): 379-382. doi: 10.1016/j.cclet.2018.08.006 shu

Mn(Ⅲ)-mediated radical cascade reaction of boronic acids with isocyanides: Synthesis of diimide derivatives

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, China

shunyi@suda.edu.cn

shunjun@suda.edu.cn

Received Date: 5 July 2018
Revised Date: 23 July 2018
Accepted Date: 11 August 2018
Available Online: 18 February 2018

Figures(6)

A manganese(Ⅲ)-promoted oxidative radical cascade reaction of easily accessible arylboronic acids with isocyanides to construct diimide derivatives was studied. This protocol provides a new way to synthesis of acetyl diimide derivatives. New C—C, C—N and C=O bonds were formed in one step.
- Mn(OAc)₃,
- Isocyanide,
- Arylboronic acid,
- Diimide derivatives,
- Radical cascade
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