Citation: Zhou Langping, Jin Zechen, Fan Xiaoxiang, Yao Yuhua, Chen Zhaoyang, Zhang Weibing, Qian Junhong. Synthesis of 1, 8-naphthalimide-based fluorescent nano-probes and their application in pH detection[J]. Chinese Chemical Letters, ;2018, 29(10): 1500-1502. doi: 10.1016/j.cclet.2018.07.018 shu

Synthesis of 1, 8-naphthalimide-based fluorescent nano-probes and their application in pH detection

Shanghai Key Laboratory of Functional Materials Chemistry, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Zhang Weibing, weibingzhang@ecust.edu.cn Qian Junhong, junhongqian@ecust.edu.cn

Received Date: 14 June 2018
Revised Date: 25 July 2018
Accepted Date: 26 July 2018
Available Online: 26 October 2018

Figures(6)

Two kinds of fluorescent nano-probes (pH-A and pH-B) with different diameters for the determination of H⁺ concentration, based on photo-induced electron transfer mechanism, were synthesized through click reaction. In which 1, 8-naphthalimide was employed as the fluorophore and N, N-dimethylethylenediamine as the receptor. The effects of particle size and linker length on the photophysical properties of the probe were studied. The results revealed that the nano-probes were more sensitive toward pH with increasing particle size. The fluorescence intensity at 529 nm (I529) of the nano-probe pH-A of 120 nm exhibited good linear relationship with solution's pH in the range of 6-8. The probe pH-A displayed excellent selectivity and competition toward proton over other possible coexisted ions, and it could be applied to detect pH in realistic samples (river water, urine).
- Fluorescent probe,
- Nano-particles,
- Naphthalimide,
- pH detection,
- Realistic samples
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