Citation: Bian Hang, Zhang Xuejian, Huang Dexin, Zhang Ning. Selective modification of two-dimensional MoS₂ nanosheets by polymer grafting[J]. Chinese Chemical Letters, ;2019, 30(2): 311-313. doi: 10.1016/j.cclet.2018.07.002 shu

Selective modification of two-dimensional MoS₂ nanosheets by polymer grafting

a.
School of Material Science and Engineering, Jilin Jianzhu University, Changchun 130118, China
b.
Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

ning.zhang@ciac.ac.cn

Received Date: 30 May 2018
Revised Date: 27 June 2018
Accepted Date: 3 July 2018
Available Online: 7 February 2018

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As an emerging two-dimensional (2D) nanomaterial, single layer or a few layers of molybdenum disulfide (MoS₂) has drawn significant attention in the past decade. In the present work, we report a strategy in direct creating polymer brushes on MoS₂ surfaces via S-C bond in the presence of UV light. The modification of MoS₂ nanosheets can be achieved bilaterally or homolaterally by performing the UV-grafting polymerization on exfoliated MoS₂ nanosheets or a single layer of MoS₂ deposited on a silicon substrate. A series of vinyl monomers including methyl methacrylate (MMA), styrene (St) and 2-isopropenyl-2-oxazoline (IPOx) could be applied to this approach, leading to the formation of poly (methyl methacrylate) (PMMA), polystyrene (PS) and poly(2-isopropenyl-2-oxazoline) (PIPOx) brushes. AFM, IR, and XPS characterizations indicate the successful formation of homogeneous brush layers on MoS₂ surfaces. The polymer brushes modified MoS₂ may found potential applications in photo dynamic therapy and sensing technologies.
- Molybdenum disulfide,
- Polymer brushes,
- SIPGP,
- Surface modification,
- S-C bond
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Selective modification of two-dimensional MoS2 nanosheets by polymer grafting

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通讯作者: 陈斌, bchen63@163.com

Selective modification of two-dimensional MoS₂ nanosheets by polymer grafting