Citation: Liang Xuemei, Wang Lei, Jeong Kwangun, Lee Myonghoon. Supramolecular conducting microfibers from amphiphilic tetrathiafulvalene-based organogelator[J]. Chinese Chemical Letters, ;2019, 30(1): 123-126. doi: 10.1016/j.cclet.2018.07.001 shu

Supramolecular conducting microfibers from amphiphilic tetrathiafulvalene-based organogelator

a.
College of Information Technology, Jilin Agricultural University, Changchun 130118, China
b.
Department of Polymer/Nano Science and Technology, Chonbuk National University, Jeonju 561756, Republic of Korea
c.
National Center for Nanoscience and Technology(NCNST), Beijing 100190, China

Corresponding author: Jeong Kwangun, kujeong@jbnu.ac.kr Lee Myonghoon, mhlee2@jbnu.ac.kr
Received Date: 26 April 2018
Revised Date: 28 June 2018
Accepted Date: 2 July 2018
Available Online: 4 January 2018

Figures(4)

An amphiphilic tetrathiafulvalene molecule was designed and readily synthesized. The am-TTF can gelate a variety of organic solvents in view of multiple intermolecular interactions, especially in polar solvent. SEM observation provided clear evidence for the self-assembled micro/nanofibers morphologies in gelation state. Moreover, XRD measurements indicated the formation of highly-ordered columnar structures. The FT-IR spectra revealed that the formation of mixed-valence states with the absorption over 1700 cm^-1, showing the semiconductive behaviors with the conductivity of 10^-4 S/cm. The am-TTF based conducting fibers could be promising candidates for organic electronics.
- Tetrathiafulvalene,
- Fiber,
- Gelator,
- Supramolecular,
- Conducting
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1.
沈阳化工大学材料科学与工程学院沈阳 110142