Citation: Yang Xuanyu, Cheng Xiaowei, Elzatahry Ahmed A., Chen Jinyang, Alghamdi Abdulaziz, Deng Yonghui. Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe₂O₃ nanoparticles for removal of organics under mild conditions[J]. Chinese Chemical Letters, ;2019, 30(2): 324-330. doi: 10.1016/j.cclet.2018.06.026 shu

Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe₂O₃ nanoparticles for removal of organics under mild conditions

a.
Department of Chemistry, State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai 200433, China
b.
Materials Science and Technology Program, College of Arts and Sciences, Qatar University, Doha, 2713, Qatar
c.
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
d.
Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
e.
State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

xwcheng@fudan.edu.cn

aelzatahry@qu.edu.qa

Received Date: 9 May 2018
Revised Date: 8 June 2018
Accepted Date: 26 June 2018
Available Online: 28 February 2018

Figures(5)

A versatile wet impregnation method was employed to conveniently and controllably deposit Fe₂O₃ nanoparticles on zeolites including commercial Y, mordenite and ZSM-5 with the similar framework Si/Al ratios and crystal sizes, respectively. The ultrafine Fe₂O₃ nanoparticles in size of 5 nm can be highly dispersed on zeolite Y matrix due to its much better wettability than ZSM-5 and mordenite. By using the obtained Fe₂O₃/zeolite composite as the heterogeneous Fenton-like catalysts, the degradation of phenol as a model reaction was systematically investigated, including the zeolite supports, particle size and dispersion of Fe₂O₃, and reaction conditions of H₂O₂ concentration, temperature, and pH value. The catalyst based on zeolite Y with Fe loading of 9% exhibited the best phenol degradation efficiency (> 90%) in neutral pH within 2 h. Its high catalytic activity in Fenton reaction can be attributed to the bifunctional properties of strong surface Brønsted acidity and high reactivity of octahedral Fe³⁺ in the highly-dispersed ultrafine Fe₂O₃ nanoparticles in size of 5 nm, which were the primary active centers to quickly decompose H₂O₂ into hydroxyl radicals. Since phenol degradation can be performed under mild conditions of ambient temperature (283-323 K) and a wide pH range (4.0-7.0), the catalysts can be easily recovered for recyclable use with stable degradation activity, which own the immense potential in deep treatment of organic pollutants in industrial wastewater.
- Fenton-like reaction,
- Zeolite,
- Fe₂O₃ nanoparticles,
- Highly-dispersed,
- Phenol degradation
1. [1]
  S. Esplugas, J. Giménez, S. Contreras, E. Pascual, M. Rodrı'Guez, Water Res. 36(2002) 1034-1042. doi: 10.1016/S0043-1354(01)00301-3
2. [2]
  P.R. Gogate, A.B. Pandit, Adv. Environ. Res. 8(2004) 553-597. doi: 10.1016/S1093-0191(03)00031-5
3. [3]
  E.R. Bandala, M.A. Peláez, D.D. Dionysiou, et al., J. Photoch. Photobiol. A 186(2007) 357-363. doi: 10.1016/j.jphotochem.2006.09.005
4. [4]
  N.K. Daud, B.H. Hameed, J. Hazard. Mater. 176(2010) 938-944. doi: 10.1016/j.jhazmat.2009.11.130
5. [5]
  V. Kavitha, K. Palanivelu, Water Res. 39(2005) 3062-3072. doi: 10.1016/j.watres.2005.05.011
6. [6]
  O. Primo, A. Rueda, M.J. Rivero, I. Ortiz, Ind. Eng. Chem. Res. 47(2008) 946-952. doi: 10.1021/ie071111a
7. [7]
  M.S. Yalfani, S. Contreras, F. Medina, J. Sueiras, Appl. Catal. B:Environ. 89(2009) 519-526. doi: 10.1016/j.apcatb.2009.01.007
8. [8]
  E. Brillas, I. Sire's, M.A. Oturan, Chem. Rev. 109(2009) 6570-6631. doi: 10.1021/cr900136g
9. [9]
  F. Pardo, J.M. Rosas, A. Santos, A. Romero, Environ. Sci. Pollut. R 21(2014) 12198-12207. doi: 10.1007/s11356-014-2997-2
10. [10]
  P.R. Gogate, A.B. Pandit, Adv. Environ. Res. 8(2004) 501-551. doi: 10.1016/S1093-0191(03)00032-7
11. [11]
  Y. Lee, L. Kovalova, C.S. Mcardell, U.V. Gunten, Water Res. 64(2014) 134-148. doi: 10.1016/j.watres.2014.06.027
12. [12]
  S. Malato, P. Fernández-Ibáñez, M.I. Maldonado, J. Blanco, W. Gernjak, Catal. Today 147(2009) 1-59. doi: 10.1016/j.cattod.2009.06.018
13. [13]
  J. Schneider, M. Matsuoka, M. Takeuchi, et al., Chem. Rev. 114(2014) 9919-9986. doi: 10.1021/cr5001892
14. [14]
  Y. Kang, K.Y. Hwang, Water Res. 34(2000) 2786-2790. doi: 10.1016/S0043-1354(99)00388-7
15. [15]
  K. Fajerwerg, H. Debellefontaine, Appl. Catal. B:Environ. 10(1996) L229-L235. doi: 10.1016/S0926-3373(96)00041-0
16. [16]
  E.V. Kuznetsova, E.N. Savinov, L.A. Vostrikova, V.N. Parmon, Appl. Catal. B:Environ. 51(2004) 165-170. doi: 10.1016/j.apcatb.2004.03.002
17. [17]
  K.A. Sashkina, V.S. Labko, N.A. Rudina, et al., J. Catal. 299(2013) 44-52. doi: 10.1016/j.jcat.2012.11.028
18. [18]
  M. Wang, G. Fang, P.D. Liu, et al., Appl. Catal. B:Environ. 188(2016) 113-122. doi: 10.1016/j.apcatb.2016.01.071
19. [19]
  J. Bujdák, Appl. Clay Sci. 34(2006) 58-73. doi: 10.1016/j.clay.2006.02.011
20. [20]
  V. Rives, M.A. Ulibarri, Coord. Chem. Rev. 181(1999) 61-120. doi: 10.1016/S0010-8545(98)00216-1
21. [21]
  E.M. Serwicka, K. Bahranowski, Catal. Today 90(2004) 85-92. doi: 10.1016/j.cattod.2004.04.012
22. [22]
  A. Vaccari, Catal. Today 41(1998) 53-71. doi: 10.1016/S0920-5861(98)00038-8
23. [23]
  Y. Han, N. Li, L. Zhao, et al., J. Phys. Chem. B 107(2003) 7551-7556. doi: 10.1021/jp026899j
24. [24]
  F. Zhang, Y. Yan, H. Yang, et al., J. Phys. Chem. B 109(2005) 8723-8732. doi: 10.1021/jp044632+
25. [25]
  D. Zhao, J. Feng, Q. Huo, et al., Science 279(1998) 548-552. doi: 10.1126/science.279.5350.548
26. [26]
  M. Neamtu, C. Catrinescu, A. Kettrup, Appl. Catal. B:Environ. 51(2004) 149-157. doi: 10.1016/j.apcatb.2004.01.020
27. [27]
  O.A. Makhotkina, E.V. Kuznetsova, S.V. Preis, Appl. Catal. B:Environ. 68(2006) 85-91. doi: 10.1016/j.apcatb.2006.07.008
28. [28]
  G. Ovejero, J.L. Sotelo, F. Martínez, J.A. Melero, L. Gordo, Ind. Eng. Chem. Res. 40(2001) 3921-3928. doi: 10.1021/ie000896g
29. [29]
  K.M. Valkaj, A. Katovic, S. Zrnčević, J. Hazard. Mater. 144(2007) 663-667. doi: 10.1016/j.jhazmat.2007.01.099
30. [30]
  X. Meng, F.S. Xiao, Chem. Rev. 114(2014) 1521-1543. doi: 10.1021/cr4001513
31. [31]
  (a) S. Navalon, M. Alvaro, H. Garcia, Appl. Catal. B: Environ. 99 (2010) 1-26;
  (b) A. Cihanoğlu, G. Gündüz, M. Dükkancı, Appl. Catal. B: Environ. 165 (2015) 687-699.
32. [32]
  M. Noorjahan, V.D. Kumari, M. Subrahmanyam, L. Panda, Appl. Catal. B:Environ. 57(2005) 291-298. doi: 10.1016/j.apcatb.2004.11.006
33. [33]
  R. Gonzalez-Olmos, F.D. Kopinke, K. Mackenzie, A. Georgi, Environ. Sci. Technol. 47(2013) 2353-2360. doi: 10.1021/es303885y
34. [34]
  K.A. Sashkina, E.V. Parkhomchuk, N.A. Rudina, V.N. Parmon, Microporous Mesoporous Mater. 189(2014) 181-188. doi: 10.1016/j.micromeso.2013.11.033
35. [35]
  G. Fierro, G. Moretti, G. Ferraris, G.B. Andreozzi, Appl. Catal. B:Environ. 102(2011) 215-223. doi: 10.1016/j.apcatb.2010.12.001
36. [36]
  G. Moretti, G. Fierro, G. Ferraris, G.B. Andreozzi, V. Naticchioni, J. Catal. 318(2014) 1-13. doi: 10.1016/j.jcat.2014.07.005
37. [37]
  K. Jíša, J. Nováková, M. Schwarze, et al., J. Catal. 262(2009) 27-34. doi: 10.1016/j.jcat.2008.11.025
38. [38]
  J. Wang, G. Mai, G. Liu, S. Yu, J. Microbiol. Biotechn. 23(2013) 251-259. doi: 10.4014/jmb
39. [39]
  P. Xie, L. Chen, Z. Ma, et al., Microporous Mesoporous Mater. 200(2014) 52-60. doi: 10.1016/j.micromeso.2014.08.020
40. [40]
  Y. Ying, S. Jiang, H. Zhang, X. Zhang, Chem. Eng. J. 259(2015) 243-251. doi: 10.1016/j.cej.2014.08.018
41. [41]
  P. Tan, J. Catal. 338(2016) 21-29. doi: 10.1016/j.jcat.2016.01.027
42. [42]
  (a) M. Takeuchi, T. Kimura, M. Hidaka, D. Rakhmawaty, M. Anpo, J. Catal. 246 (2007) 235-240;
  (b) R. Lapuente, F. Cases, P. Garce's, E. Morallo'n, J.L. Va'zquez, J. Electroanal. Chem. 451 (1998) 163-171.
43. [43]
  X. Li, X. Liu, L. Xu, et al., Appl. Catal. B:Environ. 165(2015) 79-86. doi: 10.1016/j.apcatb.2014.09.071
44. [44]
  H.V. Le, S. Parishan, A. Sagaltchik, et al., ACS Catal. 7(2017) 1403-1412. doi: 10.1021/acscatal.6b02372
45. [45]
  C. Wang, B. Zhao, Y. Xie, Chin. J. Catal. 24(2003) 475-482.
46. [46]
  M.B. Kasiri, H. Aleboyeh, A. Aleboyeh, Appl. Catal. B:Environ. 84(2008) 9-15. doi: 10.1016/j.apcatb.2008.02.024
47. [47]
  D. Wu, Y. Chen, Z. Zhang, et al., Chem. Eng. J. 294(2016) 49-57. doi: 10.1016/j.cej.2016.02.097
48. [48]
  S. Zhang, X. Zhao, H. Niu, Y. Shi, Y. Cai, J. Hazard. Mater. 167(2009) 560-566. doi: 10.1016/j.jhazmat.2009.01.024
1. [1]
  Yongheng Ren , Yang Chen , Hongwei Chen , Lu Zhang , Jiangfeng Yang , Qi Shi , Lin-Bing Sun , Jinping Li , Libo Li . Electrostatically driven kinetic Inverse CO2/C2H2 separation in LTA-type zeolites. Chinese Journal of Structural Chemistry, 2024, 43(10): 100394-100394. doi: 10.1016/j.cjsc.2024.100394
2. [2]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
3. [3]
  Jiayi Guo , Liangxiong Ling , Qinwei Lu , Yi Zhou , Xubiao Luo , Yanbo Zhou . Degradation of chloroxylenol by CoS_x activated peroxomonosulfate: Role of cobalt-sulfur ratio. Chinese Chemical Letters, 2025, 36(4): 110380-. doi: 10.1016/j.cclet.2024.110380
4. [4]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
5. [5]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
6. [6]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
7. [7]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
8. [8]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
9. [9]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
10. [10]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341
11. [11]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
12. [12]
  Tianyao He , Gan Li , Xiaoqiang Xie , Dong Han , Yunyue Leng , Qiuli Zhang , Wenming Liu , Guobo Li , Hongxiang Zhang , Shan Huang , Ting Huang , Honggen Peng . Design of highly active meso-zeolite enveloping Pt–Ni bimetallic catalysts for degradation of toluene. Chinese Chemical Letters, 2025, 36(4): 110137-. doi: 10.1016/j.cclet.2024.110137
13. [13]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
14. [14]
  Ming-Zhen Li , Yang Zhang , Kun Li , Ya-Nan Shang , Yi-Zhen Zhang , Yu-Jiao Kan , Zhi-Yang Jiao , Yu-Yuan Han , Xiao-Qiang Cao . In situ regeneration of catalyst for Fenton-like degradation by photogenerated electron transportation: Characterization, performance and mechanism comparison. Chinese Chemical Letters, 2025, 36(1): 109885-. doi: 10.1016/j.cclet.2024.109885
15. [15]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
16. [16]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
17. [17]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
18. [18]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
19. [19]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
20. [20]
  Xinyu Hou , Xuelian Yu , Meng Liu , Hengxing Peng , Lijuan Wu , Libing Liao , Guocheng Lv . Ultrafast synthesis of Mo₂N with highly dispersed Ru for efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2025, 36(4): 109845-. doi: 10.1016/j.cclet.2024.109845

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(791)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe2O3 nanoparticles for removal of organics under mild conditions

Metrics

通讯作者: 陈斌, bchen63@163.com

Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe₂O₃ nanoparticles for removal of organics under mild conditions