Citation: Yang Xuanyu, Cheng Xiaowei, Elzatahry Ahmed A., Chen Jinyang, Alghamdi Abdulaziz, Deng Yonghui. Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe₂O₃ nanoparticles for removal of organics under mild conditions[J]. Chinese Chemical Letters, ;2019, 30(2): 324-330. doi: 10.1016/j.cclet.2018.06.026 shu

Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe₂O₃ nanoparticles for removal of organics under mild conditions

a.
Department of Chemistry, State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai 200433, China
b.
Materials Science and Technology Program, College of Arts and Sciences, Qatar University, Doha, 2713, Qatar
c.
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
d.
Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
e.
State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

xwcheng@fudan.edu.cn

aelzatahry@qu.edu.qa

Received Date: 9 May 2018
Revised Date: 8 June 2018
Accepted Date: 26 June 2018
Available Online: 28 February 2018

Figures(5)

A versatile wet impregnation method was employed to conveniently and controllably deposit Fe₂O₃ nanoparticles on zeolites including commercial Y, mordenite and ZSM-5 with the similar framework Si/Al ratios and crystal sizes, respectively. The ultrafine Fe₂O₃ nanoparticles in size of 5 nm can be highly dispersed on zeolite Y matrix due to its much better wettability than ZSM-5 and mordenite. By using the obtained Fe₂O₃/zeolite composite as the heterogeneous Fenton-like catalysts, the degradation of phenol as a model reaction was systematically investigated, including the zeolite supports, particle size and dispersion of Fe₂O₃, and reaction conditions of H₂O₂ concentration, temperature, and pH value. The catalyst based on zeolite Y with Fe loading of 9% exhibited the best phenol degradation efficiency (> 90%) in neutral pH within 2 h. Its high catalytic activity in Fenton reaction can be attributed to the bifunctional properties of strong surface Brønsted acidity and high reactivity of octahedral Fe³⁺ in the highly-dispersed ultrafine Fe₂O₃ nanoparticles in size of 5 nm, which were the primary active centers to quickly decompose H₂O₂ into hydroxyl radicals. Since phenol degradation can be performed under mild conditions of ambient temperature (283-323 K) and a wide pH range (4.0-7.0), the catalysts can be easily recovered for recyclable use with stable degradation activity, which own the immense potential in deep treatment of organic pollutants in industrial wastewater.
- Fenton-like reaction,
- Zeolite,
- Fe₂O₃ nanoparticles,
- Highly-dispersed,
- Phenol degradation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe2O3 nanoparticles for removal of organics under mild conditions

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通讯作者: 陈斌, bchen63@163.com

Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe₂O₃ nanoparticles for removal of organics under mild conditions