Citation: Li Huagen, Wang Shubin, Feng Mengjie, Yang Jiping, Zhang Boming. MOF-derived ZnCo₂O₄/C wrapped on carbon fiber as anode materials for structural lithium-ion batteries[J]. Chinese Chemical Letters, ;2019, 30(2): 529-532. doi: 10.1016/j.cclet.2018.06.024 shu

MOF-derived ZnCo₂O₄/C wrapped on carbon fiber as anode materials for structural lithium-ion batteries

Key Laboratory of Aerospace Materials and Performance, School of Materials Science and Engineering, Beihang University, Beijing 100191, China

shubinwang@buaa.edu.cn

Received Date: 1 April 2018
Revised Date: 21 June 2018
Accepted Date: 25 June 2018
Available Online: 25 February 2018

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To meet the requirements for the mechanical and electrochemical performance for carbon fiber-based (CF-based) composites in the structural lithium ion batteries (SLIBs) application, better CF-Based composites are urgently needed. Herein, we report a novel composite metal organic framework (MOF)-derived ZnCo₂O₄/C@carbon fiber via a facile method and subsequent annealing treatment. In this anode, the nano ZnCo₂O₄/C coatings wrapped on the surface of CF provide more active sites for electrode reactions and the thin carbon layers give the additional protection. For this material, after 100 cycles, it exhibits excellent cycling stability including high reversible capacity of 463 mA h/g at 50 mA/g, which increases 201% than that of the CF. Thus, this structural anode material exhibits enhanced capacity, high initial columbic efficiency.
- Carbon fiber-based composite,
- Structural lithium ion batteries,
- Metal organic framework,
- High reversible capacity,
- Cycling stability
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沈阳化工大学材料科学与工程学院沈阳 110142

MOF-derived ZnCo2O4/C wrapped on carbon fiber as anode materials for structural lithium-ion batteries

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通讯作者: 陈斌, bchen63@163.com

MOF-derived ZnCo₂O₄/C wrapped on carbon fiber as anode materials for structural lithium-ion batteries