Citation: Wang Shengping, Hou Shihui, Wu Chao, Zhao Yujun, Ma Xinbin. RuCl₃ anchored onto post-synthetic modification MIL-101(Cr)-NH₂ as heterogeneous catalyst for hydrogenation of CO₂ to formic acid[J]. Chinese Chemical Letters, ;2019, 30(2): 398-402. doi: 10.1016/j.cclet.2018.06.021 shu

RuCl₃ anchored onto post-synthetic modification MIL-101(Cr)-NH₂ as heterogeneous catalyst for hydrogenation of CO₂ to formic acid

Wang Shengping ^a,b ,
Hou Shihui ^a,b ,
Wu Chao ^a,b ,
Zhao Yujun ^a,b,*, ,
Ma Xinbin ^a,b

a.
Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
b.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

yujunzhao@tju.edu.cn

Received Date: 25 April 2018
Revised Date: 7 June 2018
Accepted Date: 15 June 2018
Available Online: 18 February 2018

Figures(8)

A series of efficient ruthenium chloride (RuCl₃)-anchored MOF catalysts, such as RuCl₃@MIL-101(Cr)-Sal, and RuCl₃@MIL-101(Cr)-DPPB, have been successfully synthesized by post-synthetic modification (PSM) of the terminal amino of MIL-101(Cr)-NH₂ with salicylaldehyde, 2-diphenylphosphinobenzaldehyde (DPPBde) and anchoring of Ru(Ⅲ) ions. The stronger coordination electron donor interaction between Ru(Ⅲ) ions and chelating groups in the RuCl₃@MIL-101(Cr)-DPPB enhances its catalytic performance for CO₂ hydrogenation to formic acid. The turnover number (TON) of formic acid was up to 831 in reaction time of 2 h with dimethyl sulfoxide (DMSO) and water (H₂O) as mixed solvent, trimethylamine (Et₃N) as organic base, and PPh₃ as electronic additive.
- RuCl₃,
- MIL-101(Cr)-DPPB,
- Post-synthetic modification,
- Anchoring Ru(Ⅲ),
- Electron-donor substituent
1. [1]
  Q.Liu, L.Wu, R.Jackstell, et al., Nat.Commun.6(2015) 5933-8947. doi: 10.1038/ncomms6933
2. [2]
  M.Pérez-Fortes, J.C.Schöneberger, A.Boulamanti, et al., Int.J.Hydrogen Energy 41(2016) 16444-16462. doi: 10.1016/j.ijhydene.2016.05.199
3. [3]
  C.Federsel, R.Jackstell, M.Beller, Angew.Chem.Int.Ed.49(2010) 6254-6257. doi: 10.1002/anie.201000533
4. [4]
  K.Sordakis, C.Tang, L.K.Vogt, et al., Chem.Rev.118(2018) 372-433. doi: 10.1021/acs.chemrev.7b00182
5. [5]
  C.Hao, S.Wang, M.Li, et al., Catal.Today 160(2011) 184-190. doi: 10.1016/j.cattod.2010.05.034
6. [6]
  W.Zhang, S.Wang, Y.Zhao, et al., Chem.Lett.45(2016) 555-557. doi: 10.1246/cl.160013
7. [7]
  Z.Zhang, Y.Xie, W.Li, et al., Angew.Chem.Int.Ed.47(2008) 1127-1129.
8. [8]
  Y.M.Yu, J.H.Fei, Y.P.Zhang, et al., Chin.J.Chem.24(2006) 840-844.
9. [9]
  J.Gascon, A.Corma, F.Kapteijn, et al., ACS Catal.4(2014) 361-378. doi: 10.1021/cs400959k
10. [10]
  Y.Cui, B.Li, H.He, et al., Accounts Chem.Res.49(2016) 483-493. doi: 10.1021/acs.accounts.5b00530
11. [11]
  S.M.Cohen, Chem.Sci.1(2010) 32-36. doi: 10.1039/c0sc00127a
12. [12]
  Y.Huang, S.Liu, Z.Lin, et al., J.Catal.292(2012) 111-117. doi: 10.1016/j.jcat.2012.05.003
13. [13]
  J.Wang, M.Yang, W.Dong, et al., Catal.Sci.Technol.6(2016) 161-168. doi: 10.1039/C5CY01099C
14. [14]
  Y.Lin, C.Kong, L.Chen, RSC.Adv.2(2012) 6417-6419. doi: 10.1039/c2ra20641b
15. [15]
  Y.Y.Ohnishi, T.Matsunaga, Y.Nakao, et al., J.Am.Chem.Soc.127(2005) 4021-4032. doi: 10.1021/ja043697n
16. [16]
  J.Benitez-Garcia, G.Ruiz-Ibanez, A.Bidarian, et al., Chem.Eng.Sci.45(1990) 3407-3415. doi: 10.1016/0009-2509(90)87146-J
17. [17]
  R.J.Littel, W.P.M.V.Swaaij, G.F.Versteeg, AIChE.J.36(1990) 1633-1640.
18. [18]
  C.Yin, Z.Xu, S.Y.Yang, et al., Organometallics 20(2001) 1216-1222. doi: 10.1021/om000944x
19. [19]
  K.Rohmann, J.Kothe, M.W.Haenel, et al., Angew.Chem.Int.Ed.55(2016) 8966-8969. doi: 10.1002/anie.201603878
20. [20]
  X.Li, Y.Pi, Q.Xia, et al., Appl.Catal.B:Environ.191(2016) 192-201. doi: 10.1016/j.apcatb.2016.03.034
21. [21]
  D.Saha, R.Sen, T.Maity, et al., Langmuir 29(2013) 3140-3151. doi: 10.1021/la304147j
22. [22]
  S.Wu, L.Chen, B.Yin, et al., Chem.Com.51(2015) 9884-9887. doi: 10.1039/C5CC02741A
23. [23]
  H.Khajavi, H.A.Stil, H.P.C.E.Kuipers, et al., ACS Catal.3(2013) 2617-2626. doi: 10.1021/cs400681s
24. [24]
  S.Bhattacharyya, C.Cardinaud, G.Turban, J.Appl.Phys.83(1998) 4491-4500. doi: 10.1063/1.367211
25. [25]
  S.Bhattacharyya, J.Hong, G.Turban, J.Appl.Phys.83(1998) 3917-3919. doi: 10.1063/1.367312
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2. [2]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
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4. [4]
  Hao Wang , Meng-Qi Pan , Ya-Fei Wang , Chao Chen , Jian Xu , Yuan-Yuan Gao , Chuan-Song Qi , Wei Li , Xian-He Bu . Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes. Chinese Chemical Letters, 2024, 35(10): 109581-. doi: 10.1016/j.cclet.2024.109581
5. [5]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
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  Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
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  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
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  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
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16. [16]
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17. [17]
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RuCl3 anchored onto post-synthetic modification MIL-101(Cr)-NH2 as heterogeneous catalyst for hydrogenation of CO2 to formic acid

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通讯作者: 陈斌, bchen63@163.com

RuCl₃ anchored onto post-synthetic modification MIL-101(Cr)-NH₂ as heterogeneous catalyst for hydrogenation of CO₂ to formic acid