Citation: Yin Xianpeng, Dong Hao, Wang Shiqiang, Liang Yun, Gao Ning, Zhang Wanlin, Tian Li, Sun Fuwei, Li Guangtao. A multiple coupling approach to produce high-performance SERS substrates[J]. Chinese Chemical Letters, ;2019, 30(1): 179-182. doi: 10.1016/j.cclet.2018.06.013 shu

A multiple coupling approach to produce high-performance SERS substrates

Department of Chemistry, Key Lab of Organic Optoelectronics and Molecular Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Li Guangtao, LGT@mail.tsinghua.edu.cn
Received Date: 9 May 2018
Revised Date: 1 June 2018
Accepted Date: 7 June 2018
Available Online: 9 January 2018

Figures(4)

Creating hotspots with significantly enhanced electromagnetic (EF) field, efficiently placing target molecules in hotspot region, and achieving uniform and reproducible Raman signals are three critical issues for developing high-performance SERS substrates. In this work, large area gold nanoparticle cluster pillar array with a gold mirror at bottom was facilely fabricated by combined use of nanosphere lithography and self-assembly approach. It is both theoretically and experimentally found that through multiple coupling interactions, the electromagnetic fields at interparticle gaps within the gold clusters were significantly enhanced in our three-dimentional (3D) pillar array substrates, which can result in one order of magnitude stronger as compared with random gold clusters on a two-dimentional planar case. Due to the periodic stucture, our substrates also possess the capbility of producing highly uniform and reproducible SERS signals. Attractively, in our case, a photoresponsive polymer was used for the formation of pillar array structure. Its unique photoinduced deformation makes it possible to reversibly open and close the gaps of the closely packed Au NP array, thus enabling efficient placement or entrapment of probe molecules into hotspot sites between adjacent nanoparticles.
- Hotspots,
- Electromagnetic,
- Nanoparticles,
- Cluster array,
- SERS
1. [1]
  S.Y. Ding, E.M. You, Z.Q. Tian, M. Moskovits, Chem. Soc. Rev. 46(2017) 4042-4076. doi: 10.1039/C7CS00238F
2. [2]
  C. Hamon, L.M. Liz-Marzán, J. Colloid Interface Sci. 512(2018) 834-843. doi: 10.1016/j.jcis.2017.10.117
3. [3]
  Y.Z. Chu, M.G. Banaee, K.B. Crozier, ACS Nano 4(2010) 2804-2810. doi: 10.1021/nn901826q
4. [4]
  K.L. Kelly, E. Coronado, L.L. Zhao, G.C. Schatz, J. Phys. Chem. B 107(2003) 668-677.
5. [5]
  E. Ringe, J.M. McMahon, K. Sohn, et al., J. Phys. Chem. C 114(2010) 12511-12516. doi: 10.1021/jp104366r
6. [6]
  S.M. Nie, S.R. Emery, Science 275(1997) 1102-1106. doi: 10.1126/science.275.5303.1102
7. [7]
  S. Schlücker, Angew. Chem. Int. Ed. 53(2014) 4756-4795. doi: 10.1002/anie.201205748
8. [8]
  B. Yan, S.V. Boriskina, B.M. Reinhard, J. Phys. Chem. C 115(2011) 4578-4583. doi: 10.1021/jp112146d
9. [9]
  J.M. Nam, J.W. Oh, H. Lee, Y.D. Suh, Acc. Chem. Res. 49(2016) 2746-2755. doi: 10.1021/acs.accounts.6b00409
10. [10]
  C. Wang, L. Tian, W. Zhu, et al., Chem. Sci. 9(2018) 889-895. doi: 10.1039/C7SC03536E
11. [11]
  X.L. Zhang, X.H. Xiao, Z.G. Dai, et al., Nanoscale 9(2017) 3114-3120. doi: 10.1039/C6NR09592E
12. [12]
  H.Y. Chen, M.H. Lin, C.Y. Wang, Y.M. Chang, S. Gwo, J. Am. Chem. Soc.137(2015) 13698-13705. doi: 10.1021/jacs.5b09111
13. [13]
  E.C. Le Ru, P.G. Etchegoin, M. Meyer, J. Chem. Phys. 125(2006) 204701. doi: 10.1063/1.2390694
14. [14]
  D.D. Lin, Z.L. Wu, S.J. Li, et al., ACS Nano 11(2017) 1478-1487. doi: 10.1021/acsnano.6b06778
15. [15]
  B. Yan, A. Thubagere, W.R. Premasiri, et al., ACS Nano 3(2009) 1190-1202. doi: 10.1021/nn800836f
16. [16]
  L.L. Yang, B. Yan, W.R. Premasiri, et al., Adv. Funct. Mater. 20(2010) 2619-2628. doi: 10.1002/adfm.201000630
17. [17]
  J. Wang, L.L. Yang, S. Boriskina, B. Yan, B.M. Reinhard, Anal. Chem. 83(2011) 2243-2249. doi: 10.1021/ac103123r
18. [18]
  F.L. Yap, P. Thoniyot, S. Krishnan, S. Krishnamoorthy, ACS Nano 6(2012) 2056-2070. doi: 10.1021/nn203661n
19. [19]
  C. Leordean, M. Potara, S. Boca-Farcau, et al., J. Raman Spectrosc. 45(2014) 627-635. doi: 10.1002/jrs.v45.8
20. [20]
  W.D. Liu, B. Yang, Chin. Chem. Lett. 28(2017) 675-690. doi: 10.1016/j.cclet.2016.09.004
21. [21]
  K.N. Kanipe, P.P. Chidester, G.D. Stucky, M. Moskovits, ACS Nano 10(2016) 7566-7571. doi: 10.1021/acsnano.6b02564
22. [22]
  W.D. Li, F. Ding, J. Hu, S.Y. Chou, Opt. Express 19(2011) 3925-3936. doi: 10.1364/OE.19.003925
23. [23]
  T. Lee, J.S. Wi, A. Oh, et al., Nanoscale 10(2018) 3680-3687. doi: 10.1039/C7NR08066B
24. [24]
  M. Chirumamilla, A. Chirumamilla, A.S. Roberts, et al., Adv. Opt. Mater. 5(2017) 1600836. doi: 10.1002/adom.v5.4
25. [25]
  C.L. Haynes, R.P. Van Duyne, J. Phys. Chem. B 105(2001) 5599-5611. doi: 10.1021/jp010657m
26. [26]
  P.N. Njoki, I.I.S. Lim, D. Mott, et al., J. Phys. Chem. C 111(2007) 14664-14669. doi: 10.1021/jp074902z
27. [27]
  P. Rochon, E. Batalla, A. Natansohn, Appl. Phys. Lett. 66(1995) 136-138. doi: 10.1063/1.113541
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