Citation: Zhang Fusong, Lai Qi, Shi Xiaodong, Song Zhiguang. Triazole-gold (TAAu) catalyzed three-component coupling (A3 reaction) towards the synthesis of 2, 4-disubstituted quinoline derivatives[J]. Chinese Chemical Letters, ;2019, 30(2): 392-394. doi: 10.1016/j.cclet.2018.05.036 shu

Triazole-gold (TAAu) catalyzed three-component coupling (A3 reaction) towards the synthesis of 2, 4-disubstituted quinoline derivatives

Zhang Fusong ^a ,
Lai Qi ^a ,
Shi Xiaodong ^b,*, ,
Song Zhiguang ^a,*,

a.
Department of Chemistry, Jilin University, Changchun, Jilin 130021, China
b.
Department of Chemistry, University of South Florida, Tampa FL33620, United States

xmshi@usf.edu

szg@jlu.edu.cn

Received Date: 22 March 2018
Revised Date: 9 May 2018
Accepted Date: 22 May 2018
Available Online: 24 February 2018

Figures(2)

A gold-catalyzed three-component coupling reaction (A3 reaction) was developed as an efficient approach for the synthesis of challenging 2, 4-disubstituted quinoline derivatives. Compared to previously reported Cu/Au bi-catalyst system, this protocol enables achieving A3 reaction only in the presence of triazole-gold catalyst. Notably, 4-alkyl substituted or 2-alkyl substituted quinoline derivatives were obtained with good yields, which highlighted the unique advantage of this new strategy.
- Quinoline,
- Gold catalysis,
- A3 reaction,
- Triazole-gold
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