Citation: Li Kai, He Kunhuan, Li Quanwen, Xia Bin, Wang Qinglun, Zhang Yinghui. A zinc(Ⅱ) MOF based on secondary building units of infinite wavy-shaped chain exhibiting obvious luminescent sense effects[J]. Chinese Chemical Letters, ;2019, 30(2): 499-501. doi: 10.1016/j.cclet.2018.05.001 shu

A zinc(Ⅱ) MOF based on secondary building units of infinite wavy-shaped chain exhibiting obvious luminescent sense effects

Li Kai ^a ,
He Kunhuan ^b ,
Li Quanwen ^b ,
Xia Bin ^b ,
Wang Qinglun ^b,*, ,
Zhang Yinghui ^a,*,

a.
School of Materials Science and Engineering, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
b.
College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

wangql@nankai.edu.cn

zhangyhi@nankai.edu.cn

Received Date: 17 January 2018
Revised Date: 27 April 2018
Accepted Date: 2 May 2018
Available Online: 3 March 2018

Figures(3)

A new metal-organic framework (MOF), {[Zn₇(BPS)₄(OH)₆(H₂O)₂]·5H₂O]_n} (1), (H₂BPS = 4, 4'-bibenzoic acid-2, 2'-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and further confirmed by PXRD, TGA and IR spectrum. The solid-state emission spectra reveal that compound 1 presents strong luminescence emission bands at room temperature. The fluorescent properties of compound 1 in diverse organic solvents indicated that 1 has palpable luminescent sense effects for DMF and DMAC.
- Metal-organic frameworks,
- Secondary building unit,
- Solid-state emission spectra,
- Fluorescent properties,
- Luminescent sense effects
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