Citation: Ma Yanshuang, Zhang Liyun, Shi Wen, Niu Yiming, Zhang Bingsen, Su Dangsheng. Facile-fabricated iron oxide nanorods as a catalyst for hydrogenation of nitrobenzene[J]. Chinese Chemical Letters, ;2019, 30(1): 183-186. doi: 10.1016/j.cclet.2018.04.034 shu

Facile-fabricated iron oxide nanorods as a catalyst for hydrogenation of nitrobenzene

Ma Yanshuang ^a,b ,
Zhang Liyun ^a ,
Shi Wen ^a,b ,
Niu Yiming ^a,b ,
Zhang Bingsen ^a,, ,
Su Dangsheng ^a,,

a.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
b.
School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Zhang Bingsen, bszhang@imr.ac.cn Su Dangsheng, dssu@imr.ac.cn
Received Date: 7 March 2018
Revised Date: 19 April 2018
Accepted Date: 27 April 2018
Available Online: 30 January 2018

Figures(5)

β-FeOOH nanorods were prepared by a poly ethylene glycol (PEG) assisted precipitation of FeCl₃·6H₂O aqueous solution with urea. Na₂CO₃ aqueous solution was introduced to maintain their shapes under annealing. The one-dimensional porous iron oxide nanorods were synthesized successfully. The asprepared catalysts were characterized by X-ray diffraction, transmission electron microscopy, N₂ adsorption-desorption isotherms and X-ray photoelectron spectroscopy. The hydrogenation of nitrobenzene to aniline was taken as probe reaction to evaluate their catalytic performance. FeOOH (iron oxides hydroxide) nanorods, fabricated by annealing β-FeOOH nanorods at 250 ℃ in Ar atmosphere for 4 h, exhibited high catalytic activity for the transfer hydrogenation of nitrobenzene to aniline with hydrazine hydrate as hydrogen donors.
- Microstructure,
- β-FeOOH,
- Iron oxide hydroxide,
- Transfer hydrogenation,
- Oxygen species
1. [1]
  R.V. Jagadeesh, A.E. Surkus, H. Junge, et al., Science 342(2013) 1073-1076. doi: 10.1126/science.1242005
2. [2]
  H. Wei, X. Liu, A. Wang, et al., Nat. Commun. 5(2014) 5634. doi: 10.1038/ncomms6634
3. [3]
  D. Wang, D. Astruc, Chem. Rev. 115(2015) 6621-6686. doi: 10.1021/acs.chemrev.5b00203
4. [4]
  K.J. Datta, A.K. Rathi, P. Kumar, et al., Sci. Rep. 7(2017) 11585. doi: 10.1038/s41598-017-09477-7
5. [5]
  B. Wang, C. Li, B. He, et al., J. Energy Chem. 26(2017) 799-807. doi: 10.1016/j.jechem.2017.04.008
6. [6]
  I.T. Papadas, S. Fountoulaki, I.N. Lykakis, G.S. Armatas, Chem.-Eur. J. 22(2016) 4600-4607. doi: 10.1002/chem.201504685
7. [7]
  K.J. Datta, A.K. Rathi, M.B. Gawande, et al., ChemCatChem. 8(2016) 2351-2355. doi: 10.1002/cctc.201600296
8. [8]
  B. Chen, F. Li, Z. Huang, G. Yuan, J. Energy Chem. 25(2016) 888-894. doi: 10.1016/j.jechem.2016.06.007
9. [9]
  F. Kazemi, A.R. Kiasat, E. Sarvestani, Chin. Chem. Lett. 19(2008) 1167-1170. doi: 10.1016/j.cclet.2008.06.043
10. [10]
  C. Feng, H.Y. Zhang, N.Z. Shang, et al., Chin. Chem. Lett. 24(2013) 539-541. doi: 10.1016/j.cclet.2013.03.036
11. [11]
  H. Goksu, H. Sert, B. Kilbas, F. Sen, Curr. Org. Chem. 21(2017) 794-820. doi: 10.2174/1385272820666160525123907
12. [12]
  D. Wang, D. Astruc, Chem. Soc. Rev. 46(2017) 816-854. doi: 10.1039/C6CS00629A
13. [13]
  Y. Li, W. Shen, Chem. Soc. Rev. 43(2014) 1543-1574. doi: 10.1039/C3CS60296F
14. [14]
  A. Chen, L. Xu, X. Zhang, et al., ACS Appl. Mater. Interfaces 8(2016) 33765-33774. doi: 10.1021/acsami.6b11088
15. [15]
  X. Zhang, X. Cheng, Q. Zhang, J. Energy Chem. 25(2016) 967-984. doi: 10.1016/j.jechem.2016.11.003
16. [16]
  L. Zhang, W. Shi, B. Zhang, J. Energy Chem. 26(2017) 1117-1135. doi: 10.1016/j.jechem.2017.10.016
17. [17]
  L.S. Zhong, J.S. Hu, H.P. Liang, et al., Adv. Mater. 18(2006) 2426-2431. doi: 10.1002/(ISSN)1521-4095
18. [18]
  J. Ouyang, J. Pei, Q. Kuang, et al., ACS Appl. Mater. Interfaces 6(2014) 12505-12514. doi: 10.1021/am502358g
19. [19]
  L. Shang, T. Bian, B. Zhang, et al., Angew. Chem. Int. Ed. 126(2014) 254-258. doi: 10.1002/ange.v126.1
20. [20]
  S. Abate, G. Centi, P. Lanzafame, S. Perathoner, J. Energy Chem. 24(2015) 535-547. doi: 10.1016/j.jechem.2015.08.005
21. [21]
  S. Buller, J. Strunk, J. Energy Chem. 25(2016) 171-190. doi: 10.1016/j.jechem.2016.01.025
22. [22]
  H.Z. Cui, Y.Q. Gu, X.X. He, et al., Sci. Bull. 61(2016) 220-226. doi: 10.1007/s11434-015-0991-9
23. [23]
  L. Shang, Y. Liang, M. Li, et al., Adv. Funct. Mater. 27(2017) 1606215. doi: 10.1002/adfm.201606215
24. [24]
  J. Yang, Y. Guo, Chin. Chem. Lett. 29(2018) 252-260. doi: 10.1016/j.cclet.2017.09.013
25. [25]
  H. Niu, J. Lu, J. Song, et al., Ind. Eng. Chem. Res. 55(2016) 8527-8533. doi: 10.1021/acs.iecr.6b00984
26. [26]
  X. Mou, B. Zhang, Y. Li, et al., Angew. Chem. Int. Ed. 51(2012) 2989-2993. doi: 10.1002/anie.201107113
27. [27]
  P.C. Wu, W.S. Wang, Y.T. Huang, et al., Chem.-Eur. J. 13(2007) 3878-3885. doi: 10.1002/(ISSN)1521-3765
28. [28]
  F. Rouquerol, J. Rouquerol, K.S.W. Sing, Adsorption by Powders and Porous Solids:Principles, Methodology, and Applications, Academic Press, London, 1999.
29. [29]
  L. Zeng, K. Li, H. Wang, et al., J. Phys. Chem. C 121(2017) 12696-12710. doi: 10.1021/acs.jpcc.7b01363
30. [30]
  J.C. Dupin, D. Gonbeau, P. Vinatier, A. Levasseur, Phys. Chem. Chem. Phys. 2(2000) 1319-1324. doi: 10.1039/a908800h
31. [31]
  D. Cantillo, M.M. Moghaddam, C.O. Kappe, J. Org. Chem. 78(2013) 4530-4542. doi: 10.1021/jo400556g
32. [32]
  Q.X. Shi, R.W. Lu, K. Jin, et al., Green. Chem. 8(2006) 868-870. doi: 10.1039/b606705k
33. [33]
  G. Wienhofer, I. Sorribes, A. Boddien, et al., J. Am. Chem. Soc.133(2011) 12875-12879. doi: 10.1021/ja2061038
34. [34]
  G. Wang, H. Wang, Y. Ling, et al., Nano. Lett. 11(2011) 3026-3033. doi: 10.1021/nl201766h
1. [1]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
2. [2]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2024.100200
3. [3]
  Zhongyu Wang , Lijun Wang , Huaixin Zhao . DNA-based nanosystems to generate reactive oxygen species for nanomedicine. Chinese Chemical Letters, 2024, 35(11): 109637-. doi: 10.1016/j.cclet.2024.109637
4. [4]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
5. [5]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
6. [6]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
7. [7]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
10. [10]
  Qiuyun Li , Yannan Zhu , Yining Wang , Gang Qi , Wen-Juan Hao , Kelu Yan , Bo Jiang . Catalytic CH activation-initiated transdiannulation: An oxygen transfer route to ring-fluorinated tricyclic γ-lactones. Chinese Chemical Letters, 2024, 35(9): 109494-. doi: 10.1016/j.cclet.2024.109494
11. [11]
  Yanan Zhou , Li Sheng , Lanlan Chen , Wenhua Zhang , Jinlong Yang . Axial coordinated iron-nitrogen-carbon as efficient electrocatalysts for hydrogen evolution and oxygen redox reactions. Chinese Chemical Letters, 2025, 36(1): 109588-. doi: 10.1016/j.cclet.2024.109588
12. [12]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
13. [13]
  Jincheng Zhang , Mengjie Sun , Jiali Ren , Rui Zhang , Min Ma , Qingzhong Xue , Jian Tian . Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst. Chinese Chemical Letters, 2025, 36(1): 110491-. doi: 10.1016/j.cclet.2024.110491
14. [14]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
15. [15]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
16. [16]
  Ting Pan , Dinghu Zhang , Guomei You , Xiaoxia Wu , Chenguang Zhang , Xinyu Miao , Wenzhi Ren , Yiwei He , Lulu He , Yuanchuan Gong , Jie Lin , Aiguo Wu , Guoliang Shao . PD-L1 targeted iron oxide SERS bioprobe for accurately detecting circulating tumor cells and delineating tumor boundary. Chinese Chemical Letters, 2025, 36(1): 109857-. doi: 10.1016/j.cclet.2024.109857
17. [17]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
18. [18]
  Guoliang Liu , Zhiqiang Liu , Anmin Zheng . Modulation of zeolite surface realizes dynamic copper species redispersion. Chinese Journal of Structural Chemistry, 2024, 43(6): 100308-100308. doi: 10.1016/j.cjsc.2024.100308
19. [19]
  Shaoming Dong , Yiming Niu , Yinghui Pu , Yongzhao Wang , Bingsen Zhang . Subsurface carbon modification of Ni-Ga for improved selectivity in acetylene hydrogenation reaction. Chinese Chemical Letters, 2024, 35(12): 109525-. doi: 10.1016/j.cclet.2024.109525
20. [20]
  Jinyuan Cui , Tingting Yang , Teng Xu , Jin Lin , Kunlong Liu , Pengxin Liu . Hydrogen spillover enhances the selective hydrogenation of α,β-unsaturated aldehydes on the Cu-O-Ce interface. Chinese Journal of Structural Chemistry, 2025, 44(1): 100438-100438. doi: 10.1016/j.cjsc.2024.100438

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(742)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142