Citation: Chen Yawei, Niu Shuzhang, Lv Wei, Zhang Chen, Yang Quanhong. Promoted conversion of polysulfides by MoO₂ inlaid ordered mesoporous carbons towards high performance lithium-sulfur batteries[J]. Chinese Chemical Letters, ;2019, 30(2): 521-524. doi: 10.1016/j.cclet.2018.04.019 shu

Promoted conversion of polysulfides by MoO₂ inlaid ordered mesoporous carbons towards high performance lithium-sulfur batteries

Chen Yawei ^a ,
Niu Shuzhang ^b ,
Lv Wei ^a ,
Zhang Chen ^c,*, ,
Yang Quanhong ^d,*

a.
Engineering Laboratory for Functionalized Carbon Materials, Shenzhen Key Laboratory for Graphene-based Materials, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China
b.
Tsinghua-Berkeley Shenzhen Institute, Tsinghua University, Shenzhen 518055, China
c.
School of Marine Science and Technology, Tianjin University, Tianjin 300072, China
d.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

zhangc@tju.edu.cn

Received Date: 7 February 2018
Revised Date: 12 April 2018
Accepted Date: 16 April 2018
Available Online: 18 February 2018

Figures(4)

As polar materials, transition-metal oxides have shown great potentials to improve the adsorption of lithium polysulfides in lithium-sulfur batteries. Herein, a MoO₂-ordered mesoporous carbon (M-OMC) hybrid was designed as the sulfur host, in which MoO₂ is inlaid on the surface of ordered mesoporous carbons that can store active materials and provide fast electron transfer channel due to its ordered pore structure. The MoO₂ can effectively prevent the migration of polysulfides through the chemical adsorption and promote the conversion of polysulfides towards Li-sulfur battery.
- Lithium-sulfur batteries,
- Ordered mesoporous carbon,
- Electron transportation,
- Chemical adsorption,
- Catalytic effect,
- Polysulfides shuttling
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Promoted conversion of polysulfides by MoO2 inlaid ordered mesoporous carbons towards high performance lithium-sulfur batteries

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通讯作者: 陈斌, bchen63@163.com

Promoted conversion of polysulfides by MoO₂ inlaid ordered mesoporous carbons towards high performance lithium-sulfur batteries