Citation: Yang Youdi, Li Shaopeng, Xie Chao, Liu Hangyu, Wang Yanyan, Mei Qingqing, Liu Huizhen, Han Buxing. Ethylenediamine promoted the hydrogenative coupling of nitroarenes over Ni/C catalyst[J]. Chinese Chemical Letters, ;2019, 30(1): 203-206. doi: 10.1016/j.cclet.2018.04.006 shu

Ethylenediamine promoted the hydrogenative coupling of nitroarenes over Ni/C catalyst

Yang Youdi ^a,b ,
Li Shaopeng ^a,b ,
Xie Chao ^a,b ,
Liu Hangyu ^a,b ,
Wang Yanyan ^a,b ,
Mei Qingqing ^a ,
Liu Huizhen ^a,b,*,, ,
Han Buxing ^a,b,*,,

a.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Liu Huizhen, liuhz@iccas.ac.cn Han Buxing, hanbx@iccas.ac.cn

Received Date: 6 December 2017
Revised Date: 2 April 2018
Accepted Date: 3 April 2018
Available Online: 9 January 2018

Figures(5)

Azobenzene and its derivatives are key raw materials and it is an environmentally friendly method for the preparation of azobenzene by hydrogenative coupling of nitrobenzene. The development of nickel based catalyst for organic transformations is of importance because of its relatively low cost and toxicity. In this work, we found that ethylenediamine can enrich the electron state of Ni and make the azobenzene easily desorb from the surface of the catalyst, which inhibits the hydrogenation of azobenzene to aniline. The selectivity of azobenzene is greatly improved. When the ratio of Ni and ethylenediamine is 1:10, the yield of the azobenzene can reach 95.5%.
- Selective hydrogenation,
- Non-noble metal catalyst,
- Electronic state,
- Azobenzene,
- Organic modifiers
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