Citation: Xie Yongdi, Yuan Wenwen, Huang Yi, Wu Chunyan, Wang Haijun, Xia Yongmei, Liu Xiang. Zirconyl schiff base complex-functionalized MCM-41 catalyzes dehydration of fructose into 5-hydroxymethylfurfural in organic solvents[J]. Chinese Chemical Letters, ;2019, 30(2): 359-362. doi: 10.1016/j.cclet.2018.03.026 shu

Zirconyl schiff base complex-functionalized MCM-41 catalyzes dehydration of fructose into 5-hydroxymethylfurfural in organic solvents

Xie Yongdi ^a ,
Yuan Wenwen ^a ,
Huang Yi ^a ,
Wu Chunyan ^a ,
Wang Haijun ^a,*, ,
Xia Yongmei ^b ,
Liu Xiang ^a

a.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
b.
State Key Laboratory of Food Science & Technology, Wuxi 214122, China

wanghj329@outlook.com

Received Date: 1 February 2018
Revised Date: 5 March 2018
Accepted Date: 21 March 2018
Available Online: 21 February 2018

Figures(2)

A novel catalyst, Zr(Ⅳ)-salen-MCM-41 with Lewis acid and base sites, was prepared and characterized by FT-IR, TG, XRD, SEM, TEM, BET, NH₃-TPD, and CO₂-TPD. The as-synthesized catalyst was applied to the conversion of fructose into 5-hydroxymethylfurfural (HMF). In this work, the heterogeneous catalyst had a superior activity for the dehydration of fructose into HMF. 92.0% HMF yield was obtained from fructose at 140℃ for 4 h in dimethyl sulfoxide (DMSO). In addition, the effect of reaction temperature, reaction time, solvents and catalyst dosages were also investigated in detail. Meanwhile, the Zr(Ⅳ)-salen-MCM-41 could be reused four times with a slight decrease in catalytic activity.
- Fructose,
- 5-Hydroxymethylfurfural,
- Zirconyl Schiff base complex,
- MCM-41
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