Citation: Feng Yaping, Ding Liping, Ji Danyan, Wang Lili, Guo Wei. Highly rectified ion transport through 2D WSe₂/MoS₂ bi-layered membranes[J]. Chinese Chemical Letters, ;2018, 29(6): 892-894. doi: 10.1016/j.cclet.2018.01.053 shu

Highly rectified ion transport through 2D WSe₂/MoS₂ bi-layered membranes

Feng Yaping ^a,c ,
Ding Liping ^b ,
Ji Danyan ^a,c ,
Wang Lili ^a ,
Guo Wei ^a,,

a.
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
Center for Physiochemical Analysis and Measurement, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Guo Wei, wguo@iccas.ac.cn
Received Date: 12 January 2018
Revised Date: 19 January 2018
Accepted Date: 29 January 2018
Available Online: 1 July 2018

Figures(4)

Two-dimensional (2D) nanofluidic systems provide a highly efficient way to integrate a huge amount of cascading lamellar nanofluidic channels into macroscopic membrane materials for practical use in, for example, molecular separation, water treatment, and energy storage. Besides the well-studied graphenebased materials, other 2D nanomaterials, such as the transition metal dichalcogenides (TMDCs), are expected as promising alternatives. Here, we report strong ionic current rectification (ICR) effect found in MoS₂/WSe₂ bi-layered membrane structure. The preferential direction for ion transport is from the WSe₂ layers to the MoS₂ layers. The maximum ICR ratio approaches 35 at intermediate electrolyte concentration. More intriguingly, by exchanging the deposition order of the MoS₂ and WSe₂ layers, the observed ICR effect can be reversed. These evidences justify that the highly rectified ion transport phenomenon results from the asymmetry in the reconstructed 2D layered materials. This work is the first discovery of ICR effect in 2D nanofluidic heterostructures, and provides further opportunities for innovative nanofluidic devices and materials.
- Ion transport,
- Rectification,
- 2D materials,
- Nanofluidics,
- Heterostructure
1. [1]
  A.R. Koltonow, J. Huang, Science 351(2016) 1395-1396. doi: 10.1126/science.aaf5289
2. [2]
  Y. Feng, W. Zhu, W. Guo, L. Jiang, Adv. Mater. 29(2017) 1702773. doi: 10.1002/adma.201702773
3. [3]
  D. Li, R.B. Kaner, Science 320(2008) 1170-1171. doi: 10.1126/science.1158180
4. [4]
  W. Guo, L. Jiang, Sci. China Mater. 57(2014) 2-6. doi: 10.1007/s40843-014-0005-z
5. [5]
  G. Liu, W. Jin, N. Xu, Angew. Chem. Int. Ed. 55(2016) 13384-13397. doi: 10.1002/anie.201600438
6. [6]
  J.R. Werber, C.O. Osuji, M. Elimelech, Nat. Rev. Mater. 1(2016) 16018. doi: 10.1038/natrevmats.2016.18
7. [7]
  H.B. Park, J. Kamcev, L.M. Robeson, M. Elimelech, B.D. Freeman, Science 356(2017) eaab0530. doi: 10.1126/science.aab0530
8. [8]
  B.E. Logan, M. Elimelech, Nature 488(2012) 313-319. doi: 10.1038/nature11477
9. [9]
  J. Gao, Y.P. Feng, W. Guo, L. Jiang, Chem. Soc. Rev. 46(2017) 5400-5424. doi: 10.1039/C7CS00369B
10. [10]
  P. Sun, K. Wang, H. Zhu, Adv. Mater. 28(2016) 2287-2310. doi: 10.1002/adma.201502595
11. [11]
  M. Tsapatsis, AIChE J. 60(2014) 2374-2381. doi: 10.1002/aic.v60.7
12. [12]
  Y. Peng, Y. Li, Y. Ban, et al., Science 346(2014) 1356-1360. doi: 10.1126/science.1254227
13. [13]
  H. Cheng, Y. Zhou, Y. Feng, et al., Adv. Mater. 29(2017) 1700177. doi: 10.1002/adma.201700177
14. [14]
  J. Gao, W. Guo, H. Geng, et al., Nano Res. 5(2012) 99-108. doi: 10.1007/s12274-011-0189-7
15. [15]
  Y. Jiang, J. Gao, W. Guo, L. Jiang, Chem. Commun. 50(2014) 14149-14152. doi: 10.1039/C4CC06008C
16. [16]
  M. Chhowalla, H.S. Shin, G. Eda, et al., Nat. Chem. 5(2013) 263-275. doi: 10.1038/nchem.1589
17. [17]
  R. Lv, J.A. Robinson, R.E. Schaak, et al., Acc. Chem. Res. 48(2015) 56-64. doi: 10.1021/ar5002846
18. [18]
  Y. Hu, Y. Huang, C. Tan, et al., Mater. Chem. Front. 1(2017) 24-36. doi: 10.1039/C6QM00195E
19. [19]
  Y. Ma, B. Li, S. Yang, Mater. Chem. Front. 2(2018) 456-467. doi: 10.1039/C7QM00548B
20. [20]
  M. Zhang, C. Hou, A. Halder, H. Wang, Q. Chi, Mater. Chem. Front. 1(2017) 37-60. doi: 10.1039/C6QM00145A
21. [21]
  S. Manzeli, D. Ovchinnikov, D. Pasquier, O.V. Yazyev, A. Kis, Nat. Rev. Mater. 2(2017) 17033. doi: 10.1038/natrevmats.2017.33
22. [22]
  B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Nat. Nanotechnol. 6(2011) 147-150. doi: 10.1038/nnano.2010.279
23. [23]
  Y. Wang, C. Wang, Chin. Chem. Lett. 29(2018) 345-352. doi: 10.1016/j.cclet.2018.01.001
24. [24]
  H. Yuan, L. Kong, T. Li, Q. Zhang, Chin. Chem. Lett. 28(2017) 2180-2194. doi: 10.1016/j.cclet.2017.11.038
25. [25]
  H.Y. Chen, J. Wang, L. Meng, T. Yang, K. Jiao, Chin. Chem. Lett. 27(2016) 231-234. doi: 10.1016/j.cclet.2015.09.018
26. [26]
  H. Wang, Z. Lu, S. Xu, et al., Proc. Natl. Acad. Sci. U. S.A.110(2013) 19701-19706. doi: 10.1073/pnas.1316792110
27. [27]
  L. Sun, H. Huang, X. Peng, Chem. Commun. 49(2013) 10718-10720. doi: 10.1039/c3cc46136j
28. [28]
  W. Hirunpinyopas, E. Prestat, S.D. Worrall, et al., ACS Nano 11(2017) 11082-11090. doi: 10.1021/acsnano.7b05124
29. [29]
  W. Guo, Y. Tian, L. Jiang, Acc. Chem. Res. 46(2013) 2834-2846. doi: 10.1021/ar400024p
30. [30]
  L. Wang, Y. Feng, Y. Zhou, et al., Chem. Sci. 8(2017) 4381-4386. doi: 10.1039/C7SC00153C
31. [31]
  Z. Wang, Q. Tu, S. Zheng, et al., Nano Lett. 17(2017) 7289-7298. doi: 10.1021/acs.nanolett.7b02804
32. [32]
  M. Deng, K. Kwac, M. Li, Y. Jung, H.G. Park, Nano Lett. 17(2017) 2342-2348. doi: 10.1021/acs.nanolett.6b05238
33. [33]
  W. Guo, C. Cheng, Y. Wu, et al., Adv. Mater. 25(2013) 6064-6068. doi: 10.1002/adma.201302441
34. [34]
  J. Ji, Q. Kang, Y. Zhou, et al., Adv. Funct. Mater. 27(2017) 1603623. doi: 10.1002/adfm.v27.2
35. [35]
  J. Gao, W. Guo, D. Feng, et al., J. Am. Chem. Soc. 136(2014) 12265-12272. doi: 10.1021/ja503692z
36. [36]
  L.J. Cheng, L.J. Guo, ACS Nano 3(2009) 575-584. doi: 10.1021/nn8007542
37. [37]
  Y. Jiang, Y. Feng, J. Su, et al., J. Am. Chem. Soc. 139(2017) 18739-18746. doi: 10.1021/jacs.7b11732
38. [38]
  L.X. Cao, F.L. Xiao, Y.P. Feng, et al., Adv. Funct. Mater. 27(2017) 1604302. doi: 10.1002/adfm.201604302
39. [39]
  Z.S. Siwy, Adv. Funct. Mater. 16(2006) 735-746. doi: 10.1002/(ISSN)1616-3028
40. [40]
  W. Guo, J. Xue, L. Wang, Y. Wang, Nucl. Instrum. Meth. B 266(2008) 3095-3099. doi: 10.1016/j.nimb.2008.03.169
41. [41]
  J. Gao, A. R. Koltonow, K. Raidongia, et al., Mater. Chem. Front. 2(2018) 475-482. doi: 10.1039/C7QM00620A
1. [1]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453
2. [2]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
3. [3]
  Dai-Huo Liu , Ao Wang , Hong-Yan Lü , Xing-Long Wu , Dan Luo , Wen-Hao Li , Jin-Zhi Guo , Haozhen Dou , Qianyi Ma , Zhongwei Chen . In situ constructing (MnS/Mn₂SnS₄)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells. Chinese Chemical Letters, 2024, 35(11): 109285-. doi: 10.1016/j.cclet.2023.109285
4. [4]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
5. [5]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081
6. [6]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
7. [7]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
8. [8]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
9. [9]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
10. [10]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
11. [11]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
12. [12]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
13. [13]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
14. [14]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
15. [15]
  Jia-hui Li , Jinkai Qiu , Cheng Lian . Lithium-ion rapid transport mechanism and channel design in solid electrolytes. Chinese Journal of Structural Chemistry, 2025, 44(1): 100381-100381. doi: 10.1016/j.cjsc.2024.100381
16. [16]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
17. [17]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
18. [18]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
19. [19]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
20. [20]
  Yue Zheng , Tianpeng Huang , Pengxian Han , Jun Ma , Guanglei Cui . Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies. Chinese Journal of Structural Chemistry, 2024, 43(10): 100390-100390. doi: 10.1016/j.cjsc.2024.100390

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(710)
HTML views(55)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Highly rectified ion transport through 2D WSe2/MoS2 bi-layered membranes

Metrics

通讯作者: 陈斌, bchen63@163.com

Highly rectified ion transport through 2D WSe₂/MoS₂ bi-layered membranes