Citation: Zhang Jin, Wang Jing, Shi Zhiqiang, Xu Zhiwei. Mesoporous carbon material as cathode for high performance lithium-ion capacitor[J]. Chinese Chemical Letters, ;2018, 29(4): 620-623. doi: 10.1016/j.cclet.2018.01.031 shu

Mesoporous carbon material as cathode for high performance lithium-ion capacitor

Zhang Jin ^a ,
Wang Jing ^a ,
Shi Zhiqiang ^a,, ,
Xu Zhiwei ^b

a.
Tianjin Key Laboratory of Advanced Fiber and Energy Storage, College of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China
b.
Key Laboratory of Advanced Braided Composites, Ministry of Education, School of Textiles, Tianjin Polytechnic University, Tianjin 300387, China

Corresponding author: Shi Zhiqiang, shizhiqiang@tjpu.edu.cn
Received Date: 25 December 2017
Revised Date: 15 January 2018
Accepted Date: 17 January 2018
Available Online: 1 May 2018

Figures(4)

Mesoporous carbon (MC) material with high specific surface area (1432 m²/g), large pore volume (2.894 cm³/g) and appropriate mesopore structure (about 6.5 nm) has been prepared. We use the magnesium citrate as the precursor of the carbon material and the nano-sized magnesium oxide (MgO) particles as template provided by magnesium citrate. The structure characterization and the electrochemical performance of MC are investigated. Compared with commercial activated carbon (AC) cathode, the utilization of MC cathode can obviously improve the energy density of LIC device. When the MC cathode is coupled with pre-lithiated hard carbon (HC) anode, the LIC device shows the optimal electrochemical performance, high energy density up to 95.4 Wh/kg and power density as high as 7.4 kW/kg (based on active material mass of two electrodes), excellent capacity retention of 97.3% after 2000 cycles. The present work indicates the combination of MC electrode with HC electrodes as promising candidates for the realization of LIC with high energy density, high power density and long cycle life.
- Lithium-ion capacitors,
- Mesoporous carbon,
- Hard carbon,
- Mesocarbon microbeads,
- Pre-lithiation
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沈阳化工大学材料科学与工程学院沈阳 110142