Citation: Jiang Jiangmin, Nie Ping, Fang Shan, Zhang Yadi, An Yufeng, Fu Ruirui, Dou Hui, Zhang Xiaogang. Boron and nitrogen dual-doped carbon as a novel cathode for high performance hybrid ion capacitors[J]. Chinese Chemical Letters, ;2018, 29(4): 624-628. doi: 10.1016/j.cclet.2018.01.029 shu

Boron and nitrogen dual-doped carbon as a novel cathode for high performance hybrid ion capacitors

Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: Zhang Xiaogang, azhangxg@163.com
Received Date: 11 November 2017
Revised Date: 12 January 2018
Accepted Date: 16 January 2018
Available Online: 1 May 2018

Figures(4)

Hybrid ion capacitors have been considered as a very attractive energy source with high energy density and power density since it combines both merits of lithium ion batteries and supercapacitors. However, their commercial application has been limited by the mismatch of charge-storage capacity and electrode kinetics between the capacitor-type cathode and battery-type anode. Herein, B and N dual-doped 3D superstructure carbon cathode is prepared through a facile template method. It delivers a high specific capacity, excellent rate capability and good cycling stability due to the B, N dual-doping, which has a profound effect in control the porosity, functional groups, and electronic conductivity for the carbon cathode. The hybrid ion capacitors using B, N dual-doping carbon cathode and prelithiated graphite anode show a high energy density of 115.5 Wh/kg at 250 W/kg and remain about 53.6 Wh/kg even at a high power density of 10 kW/kg. Additionally, the novel hybrid device achieves 76.3% capacity retention after 2000 cycles tested at 1250 W/kg power density. Significantly, the simultaneous manipulation of heteroatoms in carbon materials provides new opportunities to boost the energy and power density for hybrid ion capacitors.
- Hybrid ion capacitors,
- Boron-doping,
- Nitrogen-doping,
- Dual-doped carbon,
- Template method,
- Energy density
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