Citation: Tian Jiarui, Cui Chaojie, Zheng Chao, Qian Weizhong. Mesoporous tubular graphene electrode for high performance supercapacitor[J]. Chinese Chemical Letters, ;2018, 29(4): 599-602. doi: 10.1016/j.cclet.2018.01.027 shu

Mesoporous tubular graphene electrode for high performance supercapacitor

Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Qian Weizhong, qianwz@mail.tsinghua.edu.cn
Received Date: 20 November 2017
Revised Date: 10 January 2018
Accepted Date: 15 January 2018
Available Online: 1 May 2018

Figures(4)

We report the fabrication of mesoporous tubular graphene (MTG) by a chemical vapor deposition method using MgO@ZnO core-shell structure as the template. The unique bi-directional ions transfer in unstack graphene layers and high mesopore ratio of MTGs allows capacitance reach 15 μF/cm² at 0.5 A/g, and 11 μF/cm² at 10 A/g, which is closer to theoretical value (21 μF/cm²) than SWCNTs and DWCNTs at either low or high rate. Meanwhile, MTGs exhibited good structural stability, high surface area (701 m²/g), high conductivity (30 S/cm) and low oxygen ratio (0.7 atom%), allowing excellent SC performance. The 4 V EDLC using MTGs and EMIMBF₄ electrolyte exhibited high energy density in wide range of high power density and excellent cycling stability, showing strong potential in EDLC and other electrochemical energy storage systems, in addition, showing significant factor of ion transfer distance for high performance SCs especially operating at high voltage using ionic liquid electrolyte.
- Graphene Carbon nanotube,
- Ionic liquids,
- Supercapacitor,
- Core-shell structure
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