Citation: Yoon Hee Jung, Kim Seog K., Huang Weixin, Sohn Youngku. Comparable electrocatalytic performances of carbon- and Rh-loaded SrTiO₃ nanoparticles[J]. Chinese Chemical Letters, ;2018, 29(6): 800-804. doi: 10.1016/j.cclet.2018.01.021 shu

Comparable electrocatalytic performances of carbon- and Rh-loaded SrTiO₃ nanoparticles

a.
Department of Chemistry, Yeungnam University, Gyeongsan 38541, Republic of Korea
b.
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China
c.
Department of Chemistry, Chungnam National University, Daejeon 34134, Republic of Korea

Corresponding author: Sohn Youngku, youngkusohn@cnu.ac.kr; youngkusohn@ynu.ac.kr
Received Date: 9 November 2017
Revised Date: 1 December 2017
Accepted Date: 12 January 2018
Available Online: 16 June 2018

Figures(7)

Carbon-and Rh-loaded strontium titanate (SrTiO₃) nanoparticles (NPs) were synthesized respectively by the wet impregnation method and the aerobic and anaerobic ethanol oxidation methods, and characterized by scanning electron microscopy, high resolution transmission electron microscopy, X-ray diffraction crystallography, UV-vis absorption, Raman spectroscopy, and X-ray photoelectron spectroscopy. Carbon was shown to be uniformly coated on SrTiO₃ NPs by the aerobic and anaerobic ethanol oxidation methods Electrocatalytic activities of unmodified and modified SrTiO₃ NPs were tested for water splitting and CO₂ reduction. The aerobic C-coated and Rh-loaded SrTiO₃ catalysts showed comparable activity that was increased by > 10-fold of that of unmodified SrTiO₃ catalyst. These results demonstrate that both metallic and nonmetallic surface modifications can highly improve the electrocatalytic activity of SrTiO₃ NPs and point to highlight a more important role of the modifier in the electrocatalytic reactions than of the SrTiO₃ structure.
- SrTiO₃,
- Carbon,
- Rhodium,
- Ethanol oxidation,
- Electrocatalytic water splitting,
- Electrocatalytic CO₂ reduction
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Comparable electrocatalytic performances of carbon- and Rh-loaded SrTiO3 nanoparticles

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通讯作者: 陈斌, bchen63@163.com

Comparable electrocatalytic performances of carbon- and Rh-loaded SrTiO₃ nanoparticles