Citation: Wei Zhongzhe, Li Yi, Wang Jing, Li Haoran, Wang Yong. Chemoselective hydrogenation of phenol to cyclohexanol using heterogenized cobalt oxide catalysts[J]. Chinese Chemical Letters, ;2018, 29(6): 815-818. doi: 10.1016/j.cclet.2018.01.020 shu

Chemoselective hydrogenation of phenol to cyclohexanol using heterogenized cobalt oxide catalysts

Wei Zhongzhe ^a ,
Li Yi ^b ,
Wang Jing ^b ,
Li Haoran ^b ,
Wang Yong ^b,,

a.
Institute of Industrial Catalysis, College of Chemical Engineering, State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China
b.
Advanced Materials and Catalysis Group, ZJU-NHU United R&D Center, Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Corresponding author: Wang Yong, chemwy@zju.edu.cn
Received Date: 30 September 2017
Revised Date: 29 December 2017
Accepted Date: 12 January 2018
Available Online: 1 June 2018

Figures(4)

Cyclohexanol is an important intermediate in the synthesis of Nylon-6 and plasticizers. In this work, cobalt oxide nanoparticles (NPs) supported on porous carbon (CoO_x@CN) were fabricated by one-pot method and the hybrids could efficiently and selectively hydrogenate phenol to cyclohexanol with a high yield of 98%. The high catalytic performance of CoO_x@CN was associate with the high surface area (340 m²/g) and uniformly dispersed NPs. Furthurmore, by detailed analysing the relationship between catalytic activity and catalysts composition, it clearly indicated that the Co₃O₄ in CoO_x@CN played an important role for the adsorption and activation of phenol and the in situ gernerated Co was responsible for hydrogen adsorption and dissociation. These findings provide a fundamental insight into the real active sites in hydrogenation of phenol using Co-based catalysts.
- Phenol,
- Cyclohexanol,
- Selective hydrogenation,
- Cobalt oxides,
- Metallic cobalt
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