Citation: Wang Nan, Lin Ruiyu, Xue Minzhao, Duan Yingying, Che Shun'ai. Handedness inversion of chiral mesoporous silica: A diffuse-reflectance circular dichroism study[J]. Chinese Chemical Letters, ;2019, 30(1): 139-142. doi: 10.1016/j.cclet.2018.01.008 shu

Handedness inversion of chiral mesoporous silica: A diffuse-reflectance circular dichroism study

Wang Nan ^a,1 ,
Lin Ruiyu ^a,1 ,
Xue Minzhao ^a,, ,
Duan Yingying ^b,, ,
Che Shun'ai ^a,b,,

a.
School of Chemistry and Chemical Engineering, State Key Laboratory of Composite Materials, Shanghai Jiao Tong University, Shanghai 200240, China
b.
School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: Xue Minzhao, mzxue@sjtu.edu.cn Duan Yingying, yyduan@tongji.edu.cn Che Shun'ai, chesa@sjtu.edu.cn

Received Date: 27 November 2017
Revised Date: 5 January 2018
Accepted Date: 5 January 2018
Available Online: 6 January 2018

Figures(3)

Chiral mesoporous silica ribbons and rods with inversed handedness have been synthesized with the same enantio pure N-acylaminoacidat temperatures of 0¦ and 20¦, respectively. With involving Cu²⁺ and meso-tetra(4-sulfonatophenyl) porphyrin (TPPS) as probes, ribbons and rods revealed opposite signals in diffuse-reflectance circular dichroism (DRCD) spectra, indicating the existence of inversed supramolecular chiral imprintings through helical stacking of amphiphiles. The structural evolution was systematically studied by the freeze-dried products sampled at different time after the addition of silica precursors. The H-bonding-depended molecular orientation probably controls the chiral sense upon forming chiral molecular stacking, which would be the origin of such handedness inversion phenomenon
- Chirality,
- Handedness inversion,
- Circular dichroism,
- Mesoporous,
- Amphiphile,
- Self-assembly
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